[1]罗 劲,孙 毅,陈朴青,等.侧链含三联吡啶聚甲基丙烯酸甲酯及其螯合物的制备与磁性能研究[J].江西师范大学学报(自然科学版),2018,(03):231-235.[doi:10.16357/j.cnki.issn1000-5862.2018.03.03]
　LUO Jin,SUN Yi,CHEN Puqing,et al.The Synthesis and Magnetic Properties of Metal Complexes of Polymethyl Methacrylate Containing Terpyridine[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(03):231-235.[doi:10.16357/j.cnki.issn1000-5862.2018.03.03]
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侧链含三联吡啶聚甲基丙烯酸甲酯及其螯合物的制备与磁性能研究()
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《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2018年03期
页码:
231-235
栏目:
化学与生命科学
出版日期:
2018-06-20

文章信息/Info

Title:
The Synthesis and Magnetic Properties of Metal Complexes of Polymethyl Methacrylate Containing Terpyridine
文章编号:
1000-5862(2018)03-0231-05
作者:
罗 劲1; 2; 孙 毅2; 陈朴青1; 王 涛2*; 孙维林3
1.江西师范大学分析测试中心,江西 南昌 330022; 2.江西省化学生物学重点实验室,江西师范大学化学化工学院,江西 南昌 330022; 3.浙江大学高分子科学与工程学系,浙江 杭州 310027
Author(s):
LUO Jin1; 2; SUN Yi2; CHEN Puqing1; WANG Tao2*; SUN Weilin3
1.Analytical & Testing Center,Jiangxi Normal University,Nanchang Jiangxi 330022,China; 2.Jiangxi Province Key Laboratory of Chemical Biology,College of Chemistry and Chemical Engineering,Jiangxi Normal University, Nanchang Jiangxi 330022,China; 3.Department of Polymer Science and Engineering,Zhejiang University,Hangzhou Zhejiang 310027,China
关键词:
聚[4'-(4-甲基丙烯酰氧基苯基)-2; 2':6'; 2″-三联吡啶];  螯合物;  磁性能
Keywords:
poly[4'-(4-methacryloyphenyl)-2; 2':6'; 2″-terpyridine];  complexes;  magnetic properties
分类号:
O 632.1
DOI:
10.16357/j.cnki.issn1000-5862.2018.03.03
文献标志码:
A
摘要:
以4'-(4-羟苯基)-2,2':6',2″-三联吡啶为原料合成了均聚物聚[4'-(4-甲基丙烯酰氧基苯基)-2,2':6',2″-三联吡啶](PmPhtpy),并制备了其与Co2+、Ni2+及Nd3+的高分子螯合物PmPhtpy-Co2+、PmPhtpy-Ni2+和PmPhtpy-Nd3+.聚合物及螯合物结构通过核磁共振、红外光谱和GPC进行了表征确证.螯合物PmPhtpy-Co2+、PmPhtpy-Ni2+和PmPhtpy-Nd3+的磁性能测试结果表明:PmPhtpy-Co2+和PmPhtpy-Ni2+是有机软铁磁体,PmPhtpy-Nd3+是有机软亚铁磁体.
Abstract:
Poly[4'-(4-methacryloyphenyl)-2,2':6',2″-terpyridine] and its three complexes PmPhtpy-Co2+,PmPhtpy-Ni2+,PmPhtpy-Nd3+ are synthesized using 4'-(4-methacryloyphenyl)-2,2':6',2″-terpyridine as the substrate.Their structures are fully confirmed by 1H NMR,FT-IR,and GPC.The magnetic behavior is measured as a function of the magnetic field strength at 30 kOe and as a function of temperature(5-300 K).The magnetic hysteresis loops of the complexes show a typical "S" shape at 5 K,which suggested soft ferromagnetic properties.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2017-12-17
基金项目:江西省自然科学基金(20161BAB203085)和江西省教育厅科学技术青年基金(GJJ150326)资助项目.
作者简介:罗 劲(1986-),男,江西吉安人,实验师,博士,主要从事芳杂环螯合物的合成与磁性能研究.E-mail:jinluo@jxnu.edu.cn
王 涛(1962-),男,江西吉安人,教授,博士,博士生导师,主要从事药物(绿色农药)分子设计、合成与化学生物学研究.E-mail:wangtao@jxnu.edu.cn
更新日期/Last Update: 2018-06-20