[1]尹彦冰,许钱,尹官武.不同结构的α-羰基二硫缩烯酮化合物的合成及表征[J].江西师范大学学报(自然科学版),2012,(04):412-414.
 YIN Yan-bing,XU Qian,YIN Guan-wu.The Synthesis and Characterization of Some ?-Oxo Ketene-S, S-Acetals with Different Structures[J].,2012,(04):412-414.
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不同结构的α-羰基二硫缩烯酮化合物的合成及表征()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2012年04期
页码:
412-414
栏目:
出版日期:
2012-08-01

文章信息/Info

Title:
The Synthesis and Characterization of Some ?-Oxo Ketene-S, S-Acetals with Different Structures
作者:
尹彦冰;许钱;尹官武
齐齐哈尔大学化学与化学工程学院, 黑龙江 齐齐哈尔 161006
Author(s):
YIN Yan-bing XU Qian YIN Guan-wu
关键词:
α-羰基二硫缩烯酮合成结构表征
Keywords:
?-oxo ketene-SS-acetals synthesis characterization
分类号:
Q623.5
文献标志码:
A
摘要:
以3种β-二羰基化合物为底物,用碳酸钾为拔氢试剂, N,N-二甲基甲酰胺为溶剂,分别与二硫化碳发生亲核加成,然后与不同结构卤代烃进行亲核取代合成α-羰基二硫缩烯酮.实验结果表明,该反应具有原料简单、反应条件温和、生成产物产率高等特点.用核磁、红外等测试手段对化合物进行了表征.
Abstract:
?-Oxo ketene-S,S-acetals with different structures were studied by using three β-dicarbonyl compounds as substrate, K2CO3 used as pulling hydride reagents, DMF as solvent, nucleophilic addition to carbon disulfide and nucleophilic substitution to different halogenated. Several characteristics were shown about the reaction, such as the simple raw materials, the mild reaction conditions, and the high yield production etc. Meanwhile NMR, IR and other means of methods were applied to determine the structure of the compounds.

参考文献/References:

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更新日期/Last Update: 1900-01-01