[1]卢琴芳,徐常龙,杨涛,等.介孔TiO_2/珍珠岩催化剂的制备及可见光催化活性研究[J].江西师范大学学报(自然科学版),2012,(05):530-533.
 LU Qin-fang,XU Chang-long,YANG Tao,et al.The Preparation and Photoeatalytic Activity under Visible Light of Mesoporous TiO2/EP Catalysts[J].,2012,(05):530-533.
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介孔TiO_2/珍珠岩催化剂的制备及可见光催化活性研究()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2012年05期
页码:
530-533
栏目:
出版日期:
2012-10-01

文章信息/Info

Title:
The Preparation and Photoeatalytic Activity under Visible Light of Mesoporous TiO2/EP Catalysts
作者:
卢琴芳;徐常龙;杨涛;胡庆华;赖世荣
九江学院化学与环境工程学院, 江西 九江 332005;杭州智成环境科技有限公司, 浙江 杭州 310024
Author(s):
LU Qin-fang XU Chang-long YANG Tao HU Qing-hua LAI Shi-rong
关键词:
介孔TiO2可见光珍珠岩亚甲基蓝
Keywords:
mesoporous TiO2 visible light expanded perlite methylene blue
分类号:
X783
文献标志码:
A
摘要:
为提高可见光在降解染料废水过程中的利用率,以珍珠岩为载体,制备了负载型介孔TiO2催化剂.分析了焙烧时间和负载次数对催化剂降解亚甲基蓝性能的影响及其动力学规律,并用 SEM 扫描电镜进行了形貌表征.研究结果表明:焙烧时间超过1.5 h时,催化剂活性随焙烧时间的增加而降低,在最佳焙烧时间1.5 h的条件下,可见光对亚甲基蓝的降解率达71.59;;多次负载有利于催化剂活性的提高,其中负载3次的降解效果最佳珍珠岩呈现出疏松多孔结构,珍珠岩负载1次的二氧化钛较少;负载3次的较多,分布比较均匀;负载5次的二氧化钛较集中,但不及负载3次的多.所制备的催化剂降解亚甲基蓝反应都符合一级或准一级动力学规律,其中焙烧时间为1.5 h及负载次数为3次时的一级反应速率常数分别达到最高.
Abstract:
In order to improve the utilization rate of the visible light in the degradation of dye wastewater, the light expanded perlite (EP) was selected as the carrier for preparation of the mesoporous TiO2. The effects of the roasting time and load times on the degradation of methylene blue were examined. The kinetics of photocatalytic degradation of methylene blue was studied. The morphology was characterized by SEM techniques. The results showed that the activity of catalyst decreased with the increase of the roasting time which was over 1.5 h. Under visible light irradiation for 4 h, 71.59% of methylene blue was removed over mesoporous TiO2/EP rosasted for 1.5 h. Repeated load was beneficial to improve the catalyst activity.The degradation of methylene blue were the optimisticest with loading 3 times. The EP showed a porous structure. Loading one time showed less TiO2 on the EP. Loading 3 times showed more TiO2 relatively uniform distributed. The TiO2 was more concentrated with loading 5 times than 3 times. The photodegradation profiles of the methylene blue at different roasting time and load times were fit to the first or pseudo-order kinetics equations, in which the apparent reaction rate constants reached the highest level with rosasting 1.5 h and loading 3 times respectively.

参考文献/References:

[1] Iwasaki M, Hara M, Kawada H, et al. Cobalt ion-doped TiO2 photocatalyst response to visible light [J]. Journal of Colloid and Interface Science, 2000, 224(1): 202-204.
[2] Huang Xianhao, Leal M, Li Qilin. Degradation of natural organic matter by TiO2 photocatalytic oxidation and its effect on fouling of low-pressure memabrens [J]. Water Research, 2008, 42(4/5): 1142-1150.
[3] 雷雪飞, 刘文占, 张洪林, 等. 纳米二氧化钛粉体光催化染料脱色的研究 [J]. 江西师范大学学报: 自然科学版, 2006, 30(1): 84-87.
[4] 谢倩, 赵秀兰. TiO2/AC负载型光催化剂的制备及光催化性能的研究 [J]. 西南大学学报: 自然科学版, 2011, 33(3): 63-67.
[5] 宁寻安, 袁斌, 周伟坚. 漂浮型TiO2光催化剂的研制及其除油实验研究 [J]. 工业水处理, 2008, 28(8): 28-29.
[6] 井强山, 方林霞, 郑艳萍. TiO2/膨胀珍珠岩漂浮型光催化剂制备、表征及其活性研究 [J]. 非金属矿, 2008, 31(1): 59-61.
[7] 胡庆华, 张蔚萍, 刘凌强, 等. Fe3+掺杂介孔TiO2催化降解甲基橙 [J]. 工业催化, 2009, 17(8): 66-71.
[8] Wanga W Y, Irawanb A, Kub Y. Photocatalytic degradation of Acid Red 4 using a titanium dioxide membrane supported on a porous ceramic tube [J]. Water Research, 2008, 42(19): 4725-4732.
[9] 张爱勇, 任玉辉, 肖羽堂, 等. Cu改性悬浮型光催化纳滤膜反应器处理阿特拉津溶液的降解效率及动力学研究 [J]. 环境化学, 2007, 26(6): 735-739.
[10] 廖杨槟, 孟昭福, 郑萍英. 表面活性剂光催化降解动力学研究 [J]. 环境科学学报, 2010, 30(8): 1832-1838.

更新日期/Last Update: 1900-01-01