[1]王小兵,卢文贯.超分子化合物(4-ApyH)_3(PMo_(12)O_(40))的合成、晶体结构及性质[J].江西师范大学学报(自然科学版),2013,(03):294-299.
 WANG Xiao-bing,LU Wen-guan.Synthesis, Structure and Properties of a Supramolecular Compound (4-ApyH) 3 (PMo12O40)[J].,2013,(03):294-299.
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超分子化合物(4-ApyH)_3(PMo_(12)O_(40))的合成、晶体结构及性质()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2013年03期
页码:
294-299
栏目:
出版日期:
2013-05-01

文章信息/Info

Title:
Synthesis, Structure and Properties of a Supramolecular Compound (4-ApyH) 3 (PMo12O40)
作者:
王小兵;卢文贯
韶关学院化学系,广东韶关,512005
Author(s):
WANG Xiao-bing;LU Wen-guan
关键词:
多金属氧酸盐超分子化合物晶体结构电化学光催化
Keywords:
polyoxometallatesupramolecular compoundcrystal structureelectrochemical propertyphotocatalytic activity
分类号:
O614
文献标志码:
A
摘要:
以keggin型的磷钼酸(H3PMo12O40)、4-氨基吡啶(4-Apy)为原料,在水热条件下合成了一种新的超分子化合物(4-ApyH)3(PMo12O40).通过元素分析、红外光谱和单晶X-射线衍射等确定了该化合物的组成和结构.单晶结构解析表明:该化合物是通过(PMo12O40)3-多酸阴离子和质子化的4-氨基吡啶阳离子(4-ApyH+)之间的静电引力与广泛的氢键作用形成的3维超分子结构,同时也对该化合物的电化学性质及光催化活性进行了研究.
Abstract:
A new supramolecular compound(4-ApyH)3(PMo12O40)was synthesized by hydrothermal reaction of 4-aminopyridine(4-Apy)and H3PMo12O40.Its composition and structure were characterized by elemental analysis,infrared spectroscopy and single-crystal X-ray crystallography.The result of single-crystal X-ray diffraction analysis reveals that three-dimensional(3D)structure of the title compound was formed by electrostatic attractions,and hydrogen bonding interactions between(PMo12O40) and protonated 4-aminopyridine cations(4-ApyH).In addition,the electrochemical property and photocatalytic activity of title compound were investigated as well.

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备注/Memo

备注/Memo:
国家自然科学基金(21071099);韶关学院科研基金(2011-3)
更新日期/Last Update: 1900-01-01