[1]王筠,刘芳,李全良,等.N-十二烷基丙烯酰胺的合成研究[J].江西师范大学学报(自然科学版),2013,(04):342-344.
 WANG Jun,LIU Fang,LI Quan-liang,et al.The Researches on Synthesis of N-Dodecylacrylamide[J].,2013,(04):342-344.
点击复制

N-十二烷基丙烯酰胺的合成研究()
分享到:

《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2013年04期
页码:
342-344
栏目:
出版日期:
2013-09-01

文章信息/Info

Title:
The Researches on Synthesis of N-Dodecylacrylamide
作者:
王筠;刘芳;李全良;许文俭;李铁生
周口师范学院化学系,河南周口,466000;郑州大学化学系,河南郑州,450052
Author(s):
WANG Jun;LIU Fang;LI Quan-liang;XU Wen-jian;LI Tie-sheng
关键词:
N-十二烷基丙烯酰胺合成正交试验
Keywords:
N-dodecylacrylamidesynthesisorthogonal test
分类号:
O623
文献标志码:
A
摘要:
以十二伯胺和丙烯酸为原料在室温条件下合成N-十二烷基丙烯酰胺,其结构经IR、1H NMR鉴定表征.通过单因素实验研究了溶剂种类、反应温度、反应时间及物料配比对产物产率的影响,从而建立正交实验得出合成N-十六烷基丙烯酰胺的最优工艺条件:以氯仿为溶剂,反应温度25℃,反应时间4h,物料配比为1∶1.1时,平均产率达到80;.
Abstract:
N-dodecylacrylamide was synthesised under moderate reaction condition by dodecanamine and acrylic,which was characterized by IR and H NMR.A variety of reaction effects were investigated such as solvent type,temperature,time and feed ratio which impact on the yield.Thus the optimum reaction condition of preparation of N-dodecylacrylamide obtained by orthogonal test were as follows:using trichloromethane as solvent,reaction temperature 25 ℃,reaction time 4 h,feed ratio 1.1,the average yield reached 80%.

参考文献/References:

[1] Carmen Rossini,Lucía Castillo,Andrés González.Plant extracts and their components as potential control agents against human head lice [J].Phytochemistry Reviews,2008,7(1):51-63.
[2] Larson R J,Rothgeb T M.Method for producing lower alkyl acetate [J].Catal Today,2001,69(1/2/3/4):315-322.
[3] Li T,Mitsubishi M,Miyashita T.Fabrication of nanometer scale patterns with polymer Langmuir-Blodgett films [J].Adv in Tech of Mater and Mater Proc,2005,7:209-214.
[4] Banejie A,Lando J B.Radiation-induced solid state polymerization of oriented ultrathin films of octadecylacrylamide [J].Thin Solid Films,1980,68:67-75.
[5] Guo Y,Feng F,Miyashita T.Preparation of Poly(N-alkylmethacrylamide)langmuir-blodgett films for application to a novel dry-developed positive deep UV resist [J].Macromolecules,1999,32(4):1115-1118.
[6] Mizusaki M,Kopek N,Morishima Y,et a1.Interactions of amphiphilie polyeleetrolytes and neural polymeric micelles:A study by nonradiative energy transfer [J].Langmuir,1999,15(23):8090-8099.

相似文献/References:

[1]李永双,李德江.双-三唑并[3,4-b]-[1,3,4]噻二唑类化合物的合成及抗癌活性研究[J].江西师范大学学报(自然科学版),2012,(03):297.
 LI Yong-shuang,LI De-jiang.The Synthesis and Anticancer Activities for Bis-Triazolo [3,4-b]-[1,3,4] Thiadiazole Derivatives[J].,2012,(04):297.
[2]赵三虎,康锦,康晶燕,等.一个新颖结构四核咪唑盐的合成及表征[J].江西师范大学学报(自然科学版),2012,(03):304.
 ZHAO San-hu,KANG Jin,KANG Jing-yan,et al.The Synthesis and Characterization for a Novel Structure Imidazolium Salt with Four Nuclear[J].,2012,(04):304.
[3]尹彦冰,许钱,尹官武.不同结构的α-羰基二硫缩烯酮化合物的合成及表征[J].江西师范大学学报(自然科学版),2012,(04):412.
 YIN Yan-bing,XU Qian,YIN Guan-wu.The Synthesis and Characterization of Some ?-Oxo Ketene-S, S-Acetals with Different Structures[J].,2012,(04):412.
[4]崔汉峰,袁金斌,王星,等.异丁基硼酸的超声辐射合成[J].江西师范大学学报(自然科学版),2012,(04):415.
 CUI Han-feng,YUAN Jin-bin,WANG Xing,et al.The Ultrasound Irradiation Synthesis of Isobutylbornic Acid[J].,2012,(04):415.
[5]肖伟,肖转泉,聂旭亮,等.莰烯酸酰胺的合成及其晶体结构[J].江西师范大学学报(自然科学版),2012,(05):527.
 XIAO Wei,XIAO Zhuan-quan,NIE Xu-liang,et al.The Synthesis and Crystal Structure for a New Camphene Acid Amide[J].,2012,(04):527.
[6]高明,李德江.甲氧头孢中间体7-MAC的合成工艺改进[J].江西师范大学学报(自然科学版),2012,(06):551.
 GAO Ming,LI De-jiang.The Process Improvement in the Synthetic Method of Intermediate of Methoxy Cephalosporin 7-MAC[J].,2012,(04):551.
[7]叶红德,童怀多,邹如意,等.氘代二茂铁炔酮的合成及其在机理研究中的应用[J].江西师范大学学报(自然科学版),2012,(06):558.
 YE Hong-de,TONG Huai-duo,ZOU Ru-yi,et al.The Synthesis of Deuterated Ferrocenyl Alkynone and Its Application in Mechanism Research[J].,2012,(04):558.
[8]贾晓丽,王强,宫晓瑞,等.含咔唑结构单元新型席夫碱的合成[J].江西师范大学学报(自然科学版),2012,(06):562.
 JIA Xiao-li,WANG Qiang,GONG Xiao-rui,et al.The Synthesis of Novel Schiff Base Containing Carbazole Moiety[J].,2012,(04):562.
[9]张克松,王艳玲,陈义兴,等.2-芳基-3-(3-氟苯甲酰胺基)-4-噻唑啉酮类化合物的合成及抗癌活性研究[J].江西师范大学学报(自然科学版),2013,(02):148.
 ZHANG Ke-song,WANG Yan-ling,CHEN Yi-xing,et al.Synthesis and Antibacterial Activity of 2-Aryl-3-(3-Fluorobenzoylamino)-4-Thiazolidinone[J].,2013,(04):148.
[10]喻理德,崔汉峰,王星,等.受体酪氨酸激酶抑制剂Dovitinib的合成[J].江西师范大学学报(自然科学版),2013,(02):152.
 YU Li-de,CUI Han-feng,WANG Xing,et al.The Synthesis of Tyosine Kinase Inhibitor Dovitinib[J].,2013,(04):152.

备注/Memo

备注/Memo:
国家自然科学基金(20973157)
更新日期/Last Update: 1900-01-01