[1]詹美栋,胡顺成,宋琤,等.TDPA双酮酐型聚酰亚胺合成及性能[J].江西师范大学学报(自然科学版),2015,(02):154-158.
　ZHAN Meidong,HU Shuncheng,SONG Cheng,et al.Ths Synthesis of TDPA-Polyimide and the Properties of the Adhesive Film[J].Journal of Jiangxi Normal University:Natural Science Edition,2015,(02):154-158.
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TDPA双酮酐型聚酰亚胺合成及性能()
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《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2015年02期
页码:
154-158
栏目:
出版日期:
2015-04-10

文章信息/Info

Title:
Ths Synthesis of TDPA-Polyimide and the Properties of the Adhesive Film
作者:
詹美栋；胡顺成；宋琤；宋才生
江西师范大学化学化工学院,江西 南昌 330022
Author(s):
ZHAN Meidong; HU Shuncheng; SONG Cheng; SONG Caisheng
关键词:
酮酐型聚酰亚胺;  TDPA;  封端剂
Keywords:
thermal imidization;  TDPA;  chemical imidization;  adhesion properties
分类号:
TS 174.8; TB33
文献标志码:
A
摘要:
以4,4'-对苯二甲酰二邻苯二甲酸酐(TDPA)和间苯二胺(MPD)为单体,以邻苯二甲酸酐(PA)为封端剂,采用2步法经低温溶液缩聚合成了系列结构新颖的双酮酐型聚酰亚胺(TDPA-PI).采用FT-IR、WAXD、DSC和TGA测试对聚合物的结构与性能进行了表征.考查了封端剂用量及亚胺化方法对酮酐型聚酰亚胺性能的影响.FT-IR表明,2种方法均能使TDPA-PAA亚胺化.DSC和TGA分析表明封端剂可在一定程度上提高PI的热性能,化学亚胺化得到的树脂热性能优于热亚胺化.TDPA-PI属热塑性聚合物,Tg为280.6 ℃(高于Larc-I-TPI的259 ℃),具有较好的耐热性和耐溶剂性能.
Abstract:
A novel diketone anhydride poly(ether ketone ether)imides(TDPA-PI)was synthesized via the conventional two-step by using 4,4'-terephthaloyldiphthalic anhydride(TDPA)and m-Phenylenediamine(MPD).Polyimide acid(TDPA-PAA)was end capped with the excess TDPA or small amount of phthalic anhydride(PA)and took the research of the influence to the thermodynamic property.Research the two polyimide properties which prepared by thermal and chemical imidization.The structure and properties of TDPA-PI was characterized and measured by fourier transform infrared spectroscopy(FT-IR),wide-angle X-ray diffraction(WAXD),differential scanning calorimetric(DSC),thermal gravimetric analysis(TGA)and solubility tests.FT-IR tests show that the two imidization ways both can make TDPA-PAA form an imide ring structure.DSC and TGA show that end-cap can improve Thermal properties of TDPA-PI to some extent,and the chemical imidization is superior to thermal imidization.TDPA-PI,a Thermoplastic polyimide which Tg is 280.6 ℃(above Larc-I-TPI 259 ℃)have good thermal and solvent preperties.LSS tests show that TDPA-PI has excellent adhesion properties.

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备注/Memo

备注/Memo:
国家自然科学基金(51003044)；2012年度北京分子科学国家实验室开放课题基金，江西省教育厅科技项目(GJJ12193)；江西省自然科学基金(20132BAB206035)；江西省教育厅科技落地计划(KJLD13023)
更新日期/Last Update: 1900-01-01