[1]黄维,胡娜,桂田,等.沸石咪唑酯骨架结构材料Co-ZIF-9催化氨硼烷水解制氢[J].江西师范大学学报(自然科学版),2015,(04):404-410.
 HUANG Wei,HU Na,GUI Tian,et al.The Hydrogen Generation from Hydrolysis of Ammonia Borane via Zeolitic Imidazolate Frameworks Co-ZIF-9[J].,2015,(04):404-410.
点击复制

沸石咪唑酯骨架结构材料Co-ZIF-9催化氨硼烷水解制氢()
分享到:

《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2015年04期
页码:
404-410
栏目:
出版日期:
2015-07-01

文章信息/Info

Title:
The Hydrogen Generation from Hydrolysis of Ammonia Borane via Zeolitic Imidazolate Frameworks Co-ZIF-9
作者:
黄维;胡娜;桂田;张飞;陈祥树
江西师范大学化学化工学院,江西省无机膜材料工程技术研究中心,江西 南昌 330022
Author(s):
HUANG Wei;HU Na;GUI Tian;ZHANG Fei;CHEN Xiangshu
关键词:
氨硼烷沸石咪唑酯骨架溶剂热法水解制氢
Keywords:
ammonia boraneCo-ZIF-9solvothermal methodhydrolysishydrogen generation
分类号:
TQ028.8
文献标志码:
A
摘要:
采用溶剂热方法合成了沸石咪唑酯骨架结构材料Co-ZIF-9,并将其用于非均相催化氨硼烷水解放氢实验.结果表明:配位的Co-ZIF-9在室温下能够有效地催化氨硼烷放出氢气,且其催化活性远高于Co纳米粒子,Co-ZIF-9的多孔结构在催化中起了很大的作用.另外,Co-ZIF-9催化水解氨硼烷的活化能约为40.8 kJ mol-1,低于多数用于该催化实验的其他催化剂,表明所合成的沸石咪唑酯骨架结构材料Co-ZIF-9具有优越的催化性能.
Abstract:
Crystalline zeolite imidazolate framework ZIF-9 has been prepared via solvothermal method ,and used as an efficient heterogeneous catalyst for the hydrolytic dehydrogenation of am-monia borane( AB)complex to generate a stoichiometric of hydrogen at room temperature. Co-ZIF-9 exhibited much higher catalytic activity than the bare Co nanoparticles( NPs)for hydrogen generation from the hydrolysis of AB,duo to that the porous structure of Co-ZIF-9 play an impor-tant role in the catalytic hydrolysis of AB. Additionally,the activation energy for Co-ZIF-9 was measured to be approximately of 40 . 8 kJ · mol-1 ,being lower than most of reported activation energy values for the same reaction using many different catalysts,indicating the superior catalyt-ic performance of Co-ZIF-9 .

参考文献/References:

[1] Lu Zhanghui,Xu Qiang.Recent progresses in boron- and nitrogen-based chemical hydrogen storage [J].Funct Mater Lett,2012,5(1):1230001.
[2] 张小亮,卢胜林,胡志洋,等.钯铜合金膜的化学镀制备过程研究 [J].江西师范大学学报:自然科学版,2010,34(5):516-519.
[3] Graetz J.New approaches to hydrogen storage [J].Chem Soc Rev,2009,38(1):73-82.
[4] Suh M P,Park H J,Prasad T K,et al.Hydrogen storage in metal-organic frameworks [J].Chem Rev,2012,112(2):782-835.
[5] Staubitz A,Robertson A P M,Manners I.Ammonia-borane and related compounds as dihydrogen sources [J].Chem Rev,2010,110(7):4079-4124.
[6] Yadav M,Xu Qiang.Liquid-phase chemical hydrogen storage materials [J].Energy Environ Sci,2012,5(12):9698-9725.
[7] Jiang Hailong,Xu Qiang.Catalytic hydrolysis of ammonia borane for chemical hydrogen storage [J].Catal Today,2011,170(1):56-63.
[8] Peng Bo,Chen Jun.Ammonia borane as an efficient and lightweight hydrogen storage medium [J].Energy Environ Sci,2008,1(4):479-483.
[9] Lu Zhanghui,Yao Qilu,Zhang Zhujun,et al.Nanocatalysts for hydrogen generation from ammonia borane and hydrazine borane [J].J Nanomaterials,2014,2014:729029.
[10] Yao Qilu,Lu Zhanghui,Jia Yushuai,et al.In situ facile synthesis of Rh nanoparticles supported on carbon nanotubes as highly active catalysts for H2 generation from NH3BH3 hydrolysis [J].Int J Hydrogen Energy,2015,40(5):2207-2215.
[11] Akbayrak S,Özkar S.Ruthenium(0)nanoparticles supported on multiwalled carbon nanotube as highly active catalyst for hydrogen generation from ammonia-borane [J].ACS Appl Mater Interfaces,2012,4(11):6302-6310.
[12] Yao Qilu,Shi Weimei,Feng Gang,et al.Ultrafine Ru nanoparticles embedded in SiO2 nanospheres:Highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane [J].J Power Sources,2014,257:293-299.
[13] Xi Pinxian,Chen Fengjuan,Xie Guoqiang,et al.Surfactant free RGO/Pd nanocomposites as highly active heterogeneous catalysts for the hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage [J].Nanoscale,2012,4(18):5597-5601.
[14] Chandra M,Xu Qiang.Room temperature hydrogen generation from aqueous ammonia-borane using noble metal nano-clusters as highly active catalysts [J].J Power Sources,2007,168(1):135-142.
[15] Lu Zhanghui,Jiang Hailong,Yadav M,et al.Synergistic catalysis of Au-Co@SiO2 nanospheres in hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage [J].J Mater Chem,2012,22(11):5065-5071.
[16] Dinc M,Metin Ö,Özkar S.Water soluble polymer stabilized iron(0)nanoclusters: A cost-effective and magnetically recoverable catalyst in hydrogen generation from the hydrolysis of sodium borohydride and ammonia borane [J].Catal Today,2012,183(1):10-16.
[17] Yang Yuwen,Zhang Fei,Wang Hualan,et al.Catalytic hydrolysis of ammonia borane by cobalt nickel nanoparticles supported on reduced graphene oxide for hydrogen generation [J].J Nanomater,2014,2014:294350.
[18] Song Ping,Li Yaoqi,Li Wei,et al.A highly efficient Co(0)catalyst derived from metal-organic framework for the hydrolysis of ammonia borane [J].Int J Hydrogen Energy,2011,36(1):10468-10473.
[19] Li Peizhou,Aranishi K,Xu Qiang.ZIF-8 immobilized nickel nanoparticles: highly effective catalysts for hydrogen generation from hydrolysis of ammonia borane [J].Chem Commun,2012,48(26):3173-3175.
[20] Umegaki T,Yan Junmin,Zhang Xingbo,et al.Hollow Ni-SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage [J].J Power Sources,2009,191(2):209-216.
[21] Yang Yuwen,Lu Zhanghui,Hu Yujuan,et al.Facile in situ synthesis of copper nanoparticles supported on reduced graphene oxide for hydrolytic dehydrogenation of ammonia borane [J].RSC Adv,2014,4(27):13749-13752.
[22] Yao Qilu,Huang Ming,Lu Zhanghui,et al.Methanolysis of ammonia borane by shape-controlled mesoporous copper nanostructures for hydrogen generation [J].Dalton Trans,2015,44(3):1070-1076.
[23] Yao Qilu,Lu Zhanghui,Zhang Zhujun,et al.One-pot synthesis of core-shell Cu@SiO2 nanospheres and their catalysis for hydrolytic dehydrogenation of ammonia borane and hydrazine borane [J].Sci Rep,2014,4:7597.
[24] Gu Xiaojun,Lu Zhanghui,Jiang Hailong,et al.Synergistic catalysis of metal-organic framework-immobilized Au-Pd nanoparticles in dehydrogenation of formic acid for chemical hydrogen storage [J].J Am Chem Soc,2011,133(31):11822-11825.
[25] 乔亚莉,高楼军,陈小利,等.环状双核钴配合物的合成、晶体结构及其性质 [J].江西师范大学学报:自然科学版,2012,36(4):407-411.
[26] Zhu Qilong,Li Jun,Xu Qiang.Immobilizing metal nanoparticles to metal-organic frameworks with size and location control for optimizing catalytic performance [J].J Am Chem Soc,2013,135(28):10210-10213.
[27] Battisti A,Taioli S,Garberoglio G.Zeolitic imidazolate frameworks for separation of binary mixtures of CO2,CH4,N2 and H2:A computer simulation investigation [J].Microporous Mesoporous Mater,2011,143(1):46-53.
[28] Park K S,Ni Zheng,Cote A P,et al.Exceptional chemical and thermal stability of zeolitic imidazolate frameworks [J].Proceedings of the National Academy of Sciences of the United States of America,2006,103(27):10186-10191.
[29] Li Qiming,Kim H.Hydrogen production from NaBH4 hydrolysis via Co-ZIF-9 catalyst [J].Fuel Process Technol,2012,100:43-48.
[30] Xu Qiang,Chandra M.Catalytic activities of non-noble metals for hydrogen generation from aqueous ammonia-borane at room temperature [J].J Power Sources,2006,163(1):364-370.
[31] Rachiero G P,Demirci U B,Miele P.Bimetallic RuCo and RuCu catalysts supported on γ-Al2O3.A comparative study of their activity in hydrolysis of ammonia-borane [J].Int J Hydrogen Energy,2011,36(12):7051-7065.
[32] Du Yeshuang,Cao Nan,Yang Lan,et al.One-step synthesis of magnetically recyclable rGO supported Cu@Co core-shell nanoparticles: highly efficient catalysts for hydrolytic dehydrogenation of ammonia borane and methylamine borane [J].New J Chem,2013,37(10):3035-3042.
[33] Patel N,Fernandes R,Gupta S,et al.Co-B catalyst supported over mesoporous silica for hydrogen production by catalytic hydrolysis of Ammonia Borane:A study on influence of pore structure [J].Appl Catal B-Environ,2013,140/141:125-132.
[34] Lu Zhanghui,Li Jinping,Zhu Aili,et al.Catalytic hydrolysis of ammonia borane via magnetically recyclable copper iron nanoparticles for chemical hydrogen storage [J].Int J Hydrogen Energy,2013,38(13):5330-5337.

备注/Memo

备注/Memo:
国家“863计划”新材料技术领域重大专项(2012AA03A609);国家自然科学基金(21463012,21103074);江西省重大科技创新(20114ACB01200)
更新日期/Last Update: 1900-01-01