[1]许文慧,于 颖,杨 婷,等.新型可3D打印聚酰亚胺的制备及其性能研究[J].江西师范大学学报(自然科学版),2018,(04):405-410.[doi:10.16357/j.cnki.issn1000-5862.2018.04.15]
　XU Wenhui,YU Ying,YANG Ting,et al.The Synthesis and Properties of New 3D-Printable Polyimide[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(04):405-410.[doi:10.16357/j.cnki.issn1000-5862.2018.04.15]
点击复制

新型可3D打印聚酰亚胺的制备及其性能研究()
分享到：

《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2018年04期
页码:
405-410
栏目:
出版日期:
2018-08-20

文章信息/Info

Title:
The Synthesis and Properties of New 3D-Printable Polyimide
文章编号:
1000-5862(2018)04-0405-06
作者:
许文慧; 于 颖; 杨 婷; 张春武; 侯豪情*
江西师范大学化学化工学院,江西 南昌 330022
Author(s):
XU Wenhui; YU Ying; YANG Ting; ZHANG Chunwu; HOU Haoqing*
College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang Jiangxi 330022,China
关键词:
3; 3’-RsDPA;  化学亚胺化;  聚酰亚胺;  3D打印;  热性能
Keywords:
3; 3’-RsDPA;  chemical imidization;  polyimide;  3D printing;  thermal performance
分类号:
O 211.67
DOI:
10.16357/j.cnki.issn1000-5862.2018.04.15
文献标志码:
A
摘要:
以3-氯代苯酐和间苯二酚为初始原料,合成了3,3’-(间苯)二醚二酐(3,3’-RsDPA).将其与3,3’,4,4’-联苯四甲酸二酐(BPDA)以不同比例和4,4’-二氨基二苯醚(4,4’-ODA)发生缩聚反应,以邻苯二甲酸酐(PA)为封端剂,经化学亚胺化后,制备了一系列特性粘度控制在0.47～0.48 dL·g-1的热塑性聚酰亚胺(TPI)模塑粉.采用傅里叶变换红外光谱(FT-IR)、热失重分析(TGA)、差式扫描量热仪(DSC)以及X-射线衍射(XRD)对聚酰亚胺模塑粉的结构和性能进行表征,同时考察了样品的机械性能.研究发现:当3,3’-RsDPA与BPDA的摩尔比为6:4时,共聚聚酰亚胺的性能较好,玻璃化转变温度(Tg)为252 ℃,熔融温度(Tm)为327 ℃,5%热失重温度(Td5%)为553 ℃,拉伸强度高达124 MPa,弯曲强度为175 MPa,XRD也表明该聚酰亚胺具有一定的结晶行为良好的耐热性、优异的机械性能及良好的加工性能使该聚酰亚胺材料可用于3D打印技术中.
Abstract:
A novel dianhydride,1,3-bis(2,3-dicarboxy-phenoxy)benzene dianhydride(3,3’-RsDPA)is first synthesized with 3-chlorophthalic anhydride and 1,3-benzenediol as raw materials.Then,using 3,3’-RsDPA,3,3’,4,4’-biphenyl tetracarboxylic dianhydride(BPDA)and 4,4’-oxydianiline(4,4’-ODA)as monomers,phthalic anhydride(PA)as blocking agent,a series of thermoplastic co-polyimide is synthesized which the viscosity is controlled in 0.47-0.48 dL·g-1 with different dianhydride monomers ratio followed by chemical imidization.The structure and performance of final products are characterized by FT-IR spectroscopy,thermo-gravimetric analysis(TGA),differential scanning calorimeter(DSC),X-ray diffraction(XRD).Meanwhile,the mechanical properties of the sample are investigated.The results show that when the ratio of 3,3’-RsDPA and BPDA is 6:4,the copolymerization of the polyimide has good performance,which has glass transition temperature(Tg),melting temperature(Tm)and the 5% weight loss temperature(Td5%)of 252 ℃,327 ℃ and 553 ℃,respectively.And the tensile strength is up to 124 MPa,the bending strength of 175 MPa.The XRD analysis also shows that polyimide has certain crystallization behavior.Meanwhile,the polyimide also can be printed into a variety of devices by 3D printing technology.Therefore,the as-synthesized polyimide can be used in 3D printing due to the excellent heat resistance,outstanding mechanical properties and good process ability.

参考文献/References:

[1] Williams P,Brancazio D,Cornie J.Three dimensional printing:rapid tooling and prototypes directly from a CAD model[J].Journal of Engineering for Industry,1992:114-481.
[2] Lam C X F,Mo X,Teoh S-H,et al.Scaffold development using 3D printing with a starch-based polymer[J].Materials Science and Engineering:C,2002,20(1):49-56.
[3] 陈步庆,林柳兰,陆齐,等.3维打印技术及系统研究[J].机电一体化,2005,11(4):13-15.
[4] 伍咏晖,李爱平,张曙.3维打印成形技术的新进展[J].机械制造,2005,43(12):62-64.
[5] 杜宇雷,孙菲菲,原光,等.3D打印材料的发展现状[J].徐州工程学院院报:自然科学版,2014,29(1):20-24.
[6] 张云波,乔雯钰,张鑫鑫,等.3D打印用高分子材料的研究与应用进展[J].上海塑料,2015(1):1-5.
[7] Cai H,Azangwe G,Shepherd D.Skin cell culture on an ear-shaped scaffold created by fused deposition modelling[J].Bio-Medical Materials and Engineering,2005,15(5):375-380.
[8] Rosenzweig D H,Carelli E,Steffen T,et al.3D-printed ABS and PLA scaffolds for cartilage and nucleus pulposus tissue regeneration[J].International Journal of Molecular Sciences,2015,16(7):15118-15135.
[9] Parthasarathy J.3D modeling,custom implants and its future perspectives in craniofacial surgery[J].Annals of Maxillofacial Surgery,2014,4(1):9.
[10] Schmidt M,Pohle D,Rechtenwald T.Selective laser sintering of PEEK[J].CIRP Annals-Manufacturing Technology,2007,56(1):205-208.
[11] 丁孟贤.聚酰亚胺:化学,结构与性能的关系及材料[M].北京:科学出版社,2006.
[12] Ding Mengxian.Isomeric polyimides[J].Progress in Polymer Science,2007,32(6):623-668.
[13] Liaw D-J,Wang Kungli,Huang Yingchi,et al.Advanced polyimide materials:syntheses,physical properties and applications[J].Progress in Polymer Science,2012,37(7):907-974.
[14] Hasegawa M,Horie K.Photophysics,photochemistry,and optical properties of polyimides[J].Progress in Polymer Science,2001,26(2):259-335.
[15] Ding Yichun,Hou Haoqing,Zhao Yong.Electrospun polyimide nanofibers and their applications[J].Progress in Polymer Science,2016,61:67-103.
[16] Silcox R,Bolton J S,Kim N,et al.Development of polyimide foam for aircraft sidewall applications[C].51st AIAA Aerospace Sciences Meeting Including the New Horizons Forum and Aerospace Exposition,2013:213.
[17] Liu Xiaoyan,Zhan Maosheng,Wang Kai,et al.Preparation and performance of a novel polyimide foam[J].Polymers for Advanced Technologies,2012,23(3):677-685.
[18] Wang Kunli,Liu Yiliang,Lee Jianwei,et al.Nonvolatile electrical switching and write-once read-many-times memory effects in functional polyimides containing triphenylamine and 1,3,4-oxadiazole moieties[J].Macromolecules,2010,43(17):7159-7164.
[19] Lee W.Royal aircraft establishment technical report 66409[R].August,1966.
[20] Evans T,Williams F,Donahue P,et al.Synthesis and polymerization of thioether dianhydride[R].Abstracts of Papers of the American Chemical Society,1984.
[21] Takekoshi T,Hillig W,Mellinger G,et al.NASA Contract Report[R].NASA CR-145007,1975.
[22] Uchastkina É,Kovriga V,Lur’e E,et al.Pomerantseva,physicomechanical properties of BZF polyimide[J].Plast Massy,1973(5):49-51.
[23] Tong Yuejin,Ding Mengxian,et al.Polyimides from isomeric biphenyltetracarboxylic dianhydrides and the effects of chemical structure on solubility[J].Polymer Engineering and Science,2002,42(1):101-110.
[24] Grubb T L,Ulery V L,Smith T J,et al.Highly soluble polyimides from sterically hindered diamines[J].Polymer,1999,40(15):4279-4288.
[25] 许文慧,杨婷,于颖,等.3,3’-(间苯)二醚二酐单体及其聚酰亚胺的合成与表征[J].江西师范大学学报:自然科学版,2018,42(1):82-88.
[26] Jiang Shaohua,Duan Gaigai,Chen Linlin,et al.Mechanical performance of aligned electrospun polyimide nanofiber belt at high temperature[J].Materials Letters,2015,140:12-15.

相似文献/References:

[1]李永双,李德江.双-三唑并[3,4-b]-[1,3,4]噻二唑类化合物的合成及抗癌活性研究[J].江西师范大学学报(自然科学版),2012,(03):297.
　LI Yong-shuang,LI De-jiang.The Synthesis and Anticancer Activities for Bis-Triazolo [3,4-b]-[1,3,4] Thiadiazole Derivatives[J].Journal of Jiangxi Normal University:Natural Science Edition,2012,(04):297.
[2]熊云奎,廖维林,涂媛鸿.石墨状聚萘的合成及其作为锂离子电池正极材料[J].江西师范大学学报(自然科学版),2015,(05):474.
　XIONG Yunkui,LIAO Weilin,TU Yuanhong.The Synthesis of Graphite-Like Polynaphthalene and Its Electrochemical Properties as Cathode Material for Lithium-Ion Battery[J].Journal of Jiangxi Normal University:Natural Science Edition,2015,(04):474.
[3]熊云奎.二氧化钛-聚萘/硫正电极的制备及其电化学性能[J].江西师范大学学报(自然科学版),2016,40(03):225.
　XIONG Yunkui.The Preparation and Electrochemical Performance of Titanium Dioxide-Polyperinaphthalene/Sulfur Cathode Material for Lithium-Sulfur Battery[J].Journal of Jiangxi Normal University:Natural Science Edition,2016,40(04):225.
[4]许文慧,杨 婷,于 颖,等.3,3'-(间苯)二醚二酐单体及其聚酰亚胺的合成与表征[J].江西师范大学学报(自然科学版),2018,(01):82.[doi:10.16357/j.cnki.issn1000-5862.2018.01.14]
　XU Wenhui,YANG Ting,YU Ying,et al.The Synthesis and Characterization of Polyimides from A Novel Synthesized 3,3'-(m-Phenylene)Dianhydride Monomer[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(04):82.[doi:10.16357/j.cnki.issn1000-5862.2018.01.14]
[5]刘玉婷,王龙瑞,尹大伟,等.基于肉桂醛的咪唑并[2,1-b]-1,3,4-二唑Mannich碱的合成及表征[J].江西师范大学学报(自然科学版),2021,(01):75.[doi:10.16357/j.cnki.issn1000-5862.2021.01.11]
　LIU Yuting,WANG Longrui,YIN Dawei,et al.The Synthesis and Characterization of Imidazo[2,1-b]-1,3,4-Oxadiazole Mannich Bases Based on Cinnamyl Aldehyde[J].Journal of Jiangxi Normal University:Natural Science Edition,2021,(04):75.[doi:10.16357/j.cnki.issn1000-5862.2021.01.11]

备注/Memo

备注/Memo:
收稿日期:2017-12-14
基金项目:国家自然科学基金(21174058,21374044)和江西省研究生创新基金(YC2016-B033)资助项目.
通信作者:侯豪情(1958-),男,江西鄱阳人,教授, 博士,博士生导师,主要从事高分子纳米材料研究.E-mail:hhq2001911@126.com
更新日期/Last Update: 2018-08-20