[1]时文中,徐启杰,刘雷英,等.曲克芦丁-Pd/Ce双金属催化剂对Heck反应催化性能研究[J].江西师范大学学报(自然科学版),2012,(02):189-192.
 SHI Wen-zhong,XU Qi-jie,LIU Lei-ying,et al.Catalytic Properties of Troxerutin-Pd/Ce Bimetallic Catalyst for Heck Reaction[J].Journal of Jiangxi Normal University:Natural Science Edition,2012,(02):189-192.
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曲克芦丁-Pd/Ce双金属催化剂对Heck反应催化性能研究()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2012年02期
页码:
189-192
栏目:
出版日期:
2012-03-01

文章信息/Info

Title:
Catalytic Properties of Troxerutin-Pd/Ce Bimetallic Catalyst for Heck Reaction
作者:
时文中;徐启杰;刘雷英;刘大勇;崔元臣
黄淮学院化学化工系,河南驻马店,463000;黄淮学院化学化工系,河南驻马店463000;河南大学特种功能材料重点实验室,河南开封475000;河南大学特种功能材料重点实验室,河南开封,475000
Author(s):
SHI Wen-zhong;XU Qi-jie;LIU Lei-ying;LIU Da-yong;CUI Yuan-chen
关键词:
曲克芦丁氯化钯氧化铈催化Heck反应
Keywords:
troxerutin palladium chloride ceric oxid catalysis Heck reaction
分类号:
O657.3
文献标志码:
A
摘要:
制备了曲克芦丁-Pd/Ce双金属配合物催化剂,考察了催化剂对芳基卤和取代基芳基卤与丙烯酸的 Heck芳基化反应的催化性能.结果表明:在反应温度为80℃、反应时间为8h、TBABr作为溶剂和三丁胺作为碱的条件下,曲克芦丁-Pd/Ce双金属配合物能够有效地催化Heck芳基化反应,产率达85;以上.该催化剂对不同取代基芳基卤与丙烯酸的Heck反应也有很好的催化性能.
Abstract:
The bimetallic complex of troxerutin-Pd/Ce was synthesized. The catalytic properties of complex were researched for Heck reaction of phenyl halide and substituted phenyl halide with acrylic acid.The results showed that the complex can catalyzed Heck reaction in the conditions of temperature 80 ℃, time 8 h, solvent TBABr, alkali Bu3N, and the yield can reach 85% above. It can also catalyzed the Heck reaction of substituted phenyl halide with acrylic acid well.

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更新日期/Last Update: 1900-01-01