[1]沈晓杰,张林飞,王雷,等.硫化镉空心半球的混合溶剂热合成、表征及其光学性能[J].江西师范大学学报(自然科学版),2013,(01):65-68.
 SHEN Xiao-jie,ZHANG Lin-fei,WANG Lei,et al.The CdS Hollow Hemispheres :Mixed-Solvothermal Synthesis,Characterization and Optical Properties[J].Journal of Jiangxi Normal University:Natural Science Edition,2013,(01):65-68.
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硫化镉空心半球的混合溶剂热合成、表征及其光学性能()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2013年01期
页码:
65-68
栏目:
出版日期:
2013-01-01

文章信息/Info

Title:
The CdS Hollow Hemispheres :Mixed-Solvothermal Synthesis,Characterization and Optical Properties
作者:
沈晓杰;张林飞;王雷;钟声亮
江西师范大学化学化工学院,江西南昌,330022
Author(s):
SHEN Xiao-jie;ZHANG Lin-fei;WANG Lei;ZHONG Sheng-liang
关键词:
硫化镉纳米结构空心球混合溶剂热
Keywords:
CdS nanostructure hollow sphere mixed solvothermal
分类号:
O611.4
文献标志码:
A
摘要:
在草酸的辅助下,利用混合溶剂热法首次合成了CdS空心半球,并用XRD、SEM和TEM对产物进行了表征.实验结果表明:反应时间、反应温度对产物的形貌起到一定的调控作用.另外,初步分析了CdS空心半球的形成机理,讨论了其光学性能.
Abstract:
In this work,novel cadmium sulfide(CdS)hollow hemispheres were successfully prepared via an oxalic acid-assisted solvothermal route the first time.The as-prepared products were characterized by X-ray powder diffraction(XRD),scanning electronic microscope(SEM)and transmission electron microscopy(TEM).Results show that the morphologies of the products are dependent on the reaction time and temperature.The optical properties and possible formation process for the CdS hollow hemisphere were investigated.

参考文献/References:

[1] Fang Jixiang,You Hongjun,Kong Peng,et al.Dendritic silver nanostructure growth and evolution in replacement reaction [J].Cryst Growth Des,2007,7(5):864-867.
[2] Champ S,Dickinson J A, Fallon P S,et al.Hydrogen- bonded molecular ribbons as templates for the synthesis of modified mineral phases [J].Angew Chem Int Ed,2000,39(15):2716-2719.
[3] Cölfen H,Qi Limin,Mastai Y,et al.Formation of unusual 10-petal BaSO4 structures in the presence of a polymeric additive [J].Cryst Growth Des,2002,2(3):191-196.
[4] Zhao Pingtang,Huang Kaixun.Preparation and characterization of netted sphere-like CdS nanostructures [J].Cryst Growth Des,2008,8(2):717-722.
[5] Chen Fei,Zhou Renjia,Yang Ligong,et al.Large-scale and shape-controlled syntheses of three-dimensional CdS nanocrystals with flowerlike structure [J].J Phys Chem C,2008,112(4):1001-1007.
[6] Guo Yingshu,Sun Yuanshun,Zhang Shusheng.Electrochemiluminescence induced photoelectrochemistry for sensing of the DNA based on DNA-linked CdS NPs superstructure with intercalator molecules [J].Chem Commun,2011,47:1595-1597.
[7] Zhong Shengliang,Zhang Linfei,Huang Zhenzhong,et al.Mixed-solvothermal synthesis of CdS micro/nanostructures and their optical properties [J].Appl Surf Sci,2011,257:2599-2603.
[8] Manna L,Milliron D J,Meisel A,et al.Controlled growth of tetrapod-branched inorganic nanocrystals [J].Nat Mater,2003,2(6):382-385.
[9] Xu Shu,Wang Hui,Zhu Junjie,et al.An in situ Template Route for fabricating metal chalcogenide hollow spherical assemblies sonochemically [J].Eur J Inorg Chem,2004,23:4653-4659.
[10] Zhang Jun,Sun Lingdong,Yin Jialu,et al.Control of ZnO morphology via a simple solution route [J].Chem Mater,2002,14(10):4172-4177.
[11] 张保花,郭富强.不同镉源对溶剂热合成CdS纳米晶的物质结构影响研究 [J].江西师范大学学报:自然科学版,2010,34(4):346-349.
[12] Li Yanfen,Bao Jianchun,Han Min,et al.A simple assay to amplify the electrochemical signal by the aptamer based biosensor modified with CdS hollow nanospheres [J].Biosens Bioelectron,2011,26:3531-3535.
[13] Shao Mingwang,Wang Debao,Hu Bing,et al.Self-template route to CdS hollow spheres and in situ conversion to CdS/Ag2S composite materials [J].J Cryst Growth,2003,249:549-552.
[14] Lee S M,Cho S N,Cheon J.Anisotropic shape control of colloidal inorganic nanocrystals [J].Adv Mater,2003,15(5):441-444.
[15] Dai Zhihui,Zhang Jie,Bao Jianchun,et al.Facile synthesis of high-quality nano-sized CdS hollow spheres and their application in electrogenerated chemiluminescence sensing [J].J Mater Chem,2007,17:1087-1093.
[16] Duan Shumin,Wu Qingsheng,Jia Runping,et al.Synthesis of CdS hollow/solid nanospheres and their chain-structures by membrane technique [J].J Nanopart Res,2008,10:525-529.
[17] Weller H.Colloidal semiconductor Q-particles:chemistry in the transition region between solid state and molecules [J].Angew Chem Int Ed,1993,32:41-53.

备注/Memo

备注/Memo:
国家自然科学基金(21201089,21261010);江西省教育厅科技计划课题(GJJ11382);江西省科技支撑计划课题(2010BJB01100)
更新日期/Last Update: 1900-01-01