[1]黄维,胡娜,桂田,等.沸石咪唑酯骨架结构材料Co-ZIF-9催化氨硼烷水解制氢[J].江西师范大学学报(自然科学版),2015,(04):404-410.
　HUANG Wei,HU Na,GUI Tian,et al.The Hydrogen Generation from Hydrolysis of Ammonia Borane via Zeolitic Imidazolate Frameworks Co-ZIF-9[J].Journal of Jiangxi Normal University:Natural Science Edition,2015,(04):404-410.
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沸石咪唑酯骨架结构材料Co-ZIF-9催化氨硼烷水解制氢()
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《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2015年04期
页码:
404-410
栏目:
出版日期:
2015-07-01

文章信息/Info

Title:
The Hydrogen Generation from Hydrolysis of Ammonia Borane via Zeolitic Imidazolate Frameworks Co-ZIF-9
作者:
黄维；胡娜；桂田；张飞；陈祥树
江西师范大学化学化工学院，江西省无机膜材料工程技术研究中心，江西 南昌 330022
Author(s):
HUANG Wei；HU Na；GUI Tian；ZHANG Fei；CHEN Xiangshu
关键词:
氨硼烷; 沸石咪唑酯骨架; 溶剂热法; 水解; 制氢
Keywords:
ammonia borane; Co-ZIF-9; solvothermal method; hydrolysis; hydrogen generation
分类号:
TQ028.8
文献标志码:
A
摘要:
采用溶剂热方法合成了沸石咪唑酯骨架结构材料Co-ZIF-9，并将其用于非均相催化氨硼烷水解放氢实验.结果表明：配位的Co-ZIF-9在室温下能够有效地催化氨硼烷放出氢气，且其催化活性远高于Co纳米粒子，Co-ZIF-9的多孔结构在催化中起了很大的作用.另外，Co-ZIF-9催化水解氨硼烷的活化能约为40.8 kJ mol-1，低于多数用于该催化实验的其他催化剂，表明所合成的沸石咪唑酯骨架结构材料Co-ZIF-9具有优越的催化性能.
Abstract:
Crystalline zeolite imidazolate framework ZIF-9 has been prepared via solvothermal method ,and used as an efficient heterogeneous catalyst for the hydrolytic dehydrogenation of am-monia borane( AB)complex to generate a stoichiometric of hydrogen at room temperature. Co-ZIF-9 exhibited much higher catalytic activity than the bare Co nanoparticles( NPs)for hydrogen generation from the hydrolysis of AB,duo to that the porous structure of Co-ZIF-9 play an impor-tant role in the catalytic hydrolysis of AB. Additionally,the activation energy for Co-ZIF-9 was measured to be approximately of 40 . 8 kJ · mol-1 ,being lower than most of reported activation energy values for the same reaction using many different catalysts,indicating the superior catalyt-ic performance of Co-ZIF-9 .

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备注/Memo

备注/Memo:
国家“863计划”新材料技术领域重大专项(2012AA03A609)；国家自然科学基金(21463012，21103074)；江西省重大科技创新(20114ACB01200)
更新日期/Last Update: 1900-01-01