[1]尹彦冰,宫 晶,裴笠舟.2种萘氧基MPc/TiO2复合材料的制备及其表征[J].江西师范大学学报(自然科学版),2018,(04):419-421.[doi:10.16357/j.cnki.issn1000-5862.2018.04.17]
　ZHAO Zhipeng,ZENG Chenghui,SHUAI Min,et al.The Preparation and Photoluminescence Properties of Europium Thenoyltrifluoroacetone Coordination Polymer Nanoparticles and Their Film[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(04):419-421.[doi:10.16357/j.cnki.issn1000-5862.2018.04.17]
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2种萘氧基MPc/TiO2复合材料的制备及其表征()
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《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2018年04期
页码:
419-421
栏目:
出版日期:
2018-08-20

文章信息/Info

Title:
The Preparation and Photoluminescence Properties of Europium Thenoyltrifluoroacetone Coordination Polymer Nanoparticles and Their Film
文章编号:
1000-5862(2018)04-0419-03
作者:
尹彦冰; 宫 晶; 裴笠舟
齐齐哈尔大学化学与化学工程学院,黑龙江 齐齐哈尔 161006
Author(s):
ZHAO Zhipeng; ZENG Chenghui; SHUAI Min; LIU Ran; ZHONG Shengliang*
College of Chemical and Chemistry Engineering,Jiangxi Normal University,Nanchang Jiangxi 330022,China
关键词:
萘氧基金属酞菁复合材料;  合成;  表征
Keywords:
coordination polymer;  rare earth;  thenoyltrifluoroacetone;  nanoparticles;  films
分类号:
O 621.3
DOI:
10.16357/j.cnki.issn1000-5862.2018.04.17
文献标志码:
A
摘要:
合成了萘氧基酞菁的前体化合物3-(2-萘氧基)邻苯二腈,通过1H NMR和熔点测定对其结构进行了表征,采用原位合成法合成了3-(2-萘氧基)CoPc/TiO2和3-(2-萘氧基)CuPc/TiO2复合材料,并利用IR、UV-Vis、XRD对产物进行表征,讨论了中心金属离子和负载TiO2后对酞菁Q带最大吸收波长的影响,以及负载酞菁后对TiO2晶型的影响.结果表明:复合材料Q带吸收发生一定程度红移,酞菁的负载使TiO2的晶粒变小,但晶型没有改变.
Abstract:
Europium thenoyltrifluoroacetone coordination polymer(Eu-CP)nanoparticles have been prepared via a facile solvothermal method employing Eu(NO3)3·6H2O as metal ion source,and thiophene-formyl trifluoroacetone as organic ligand.In order to study the structure and composition of precursors,a series of characterizations of the precursors are performed and their luminescence properties are studied.In addition,a series of spin-coating films of Eu-CP nanoparticles with different raw material ratios are prepared by mixing with polymethyl methacrylate and using N,N-dimethylformamide as solvent.And their fluorescence intensities are compared.Furthermore,the light stability and thermal stability of the films obtained are also investigated.

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备注/Memo

备注/Memo:
收稿日期:2017-06-02
基金项目:黑龙江省普通高等学校青年学术骨干支持计划(1153G052)和黑龙江省教育厅基本业务专项理工面上课题(135109208)资助项目.
作者简介:尹彦冰(1970-),男,黑龙江肇源人,教授,博士,主要从事有机合成及有机智能材料研究.E-mail:yinyanbing70@163.com
更新日期/Last Update: 2018-08-20