[1]林俊岳,杨杰芳,丁秋平*,等.酰胺导向Rh催化C—H键官能团化反应[J].江西师范大学学报(自然科学版),2020,(03):240-246+300.[doi:10.16357/j.cnki.issn1000-5862.2020.03.05]
 LIN Junyue,YANG Jiefang,DING Qiuping*,et al.The Amide-Directed C—H Functionalization Catalyzed by Rh-Catalysts[J].Journal of Jiangxi Normal University:Natural Science Edition,2020,(03):240-246+300.[doi:10.16357/j.cnki.issn1000-5862.2020.03.05]
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酰胺导向Rh催化C—H键官能团化反应()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2020年03期
页码:
240-246+300
栏目:
化学与生命科学
出版日期:
2020-06-10

文章信息/Info

Title:
The Amide-Directed C—H Functionalization Catalyzed by Rh-Catalysts
文章编号:
1000-5862(2020)03-0240-07
作者:
林俊岳1杨杰芳2丁秋平1*黄亚茹3龚 春2林 洪2高 伟12*
1.江西师范大学化学化工学院,江西 南昌 330022; 2.江西省林业科学院,江西 南昌 330032; 3.南昌大学附属中学,江西 南昌 330029
Author(s):
LIN Junyue1YANG Jiefang2DING Qiuping1*HUANG Yaru3GONG Chun2LIN Hong2GAO Wei12*
1.College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang Jiangxi 330022,China; 2.Jiangxi Academy of Forestry,Nanchang Jiangxi 330032,China; 3.The Attached Middle School,Nanchang University,Nanchang Jiangxi 330013,China
关键词:
Rh催化 酰胺 C—H键活化
Keywords:
Rh catalysis amide C—H bond activation
分类号:
O 621.251
DOI:
10.16357/j.cnki.issn1000-5862.2020.03.05
文献标志码:
A
摘要:
过渡金属催化的C—H键直接官能团化是构建C—C键和C—X(O,S,N等)键的新策略,目的是提供替代的、环保的、高效的途径构建C—C和C—杂键.其中酰胺导向Rh催化C—H活化官能团化引起了人们广泛关注,近年来该领域的研究已成为热点.该文综述了该策略在有机合成领域的研究进展,主要包括酰胺导向Rh催化C—H键烯、炔基化、芳基化、活化/环化和胺化反应.
Abstract:
The direct functionalizations of C—H bond catalyzed by transition metal is a new strategy to construct C—C bond and C—X(O,S,N,etc),providing an alternative,environmentally friendly and efficient way to construct C—C and C-hybrid bonds.Among them,Rh catalyzed C—H functionalizations of groups directed by amide group has attracted extensive attention.In recent years,the research in this field has become hot.The research progress of this strategy in the field of organic synthesis is provided for readers in this review,mainly including the alkynylation,arylate,activation/ cyclization and amination of C—H bond.

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备注/Memo

备注/Memo:
收稿日期:2019-09-30
基金项目:国家自然科学基金(21662017)和江西省林业局“樟树重大专项”课题资助项目.
通信作者:丁秋平(1975-),男,江西吉安人,教授,博士,博士生导师,主要从事有机合成化学研究.E-mail:1902892026@qq.com
高 伟(1986-),男,江西吉安人,助理研究员,博士,主要从事化学生物学研究.E-mail:284256805@qq.com
更新日期/Last Update: 2020-06-10