[1]赵志鹏,曾承辉,帅 敏,等.噻吩甲酰三氟丙酮铕配位聚合物纳米粒子及其薄膜的制备与光学性能研究[J].江西师范大学学报(自然科学版),2018,(04):411-418+426.[doi:10.16357/j.cnki.issn1000-5862.2018.04.16]
　YIN Yanbing,GONG Jing,PEI Lizhou.The Synthesis and Charaterization of Two Naphthyloxy MPc/TiO2 Composite[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(04):411-418+426.[doi:10.16357/j.cnki.issn1000-5862.2018.04.16]
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噻吩甲酰三氟丙酮铕配位聚合物纳米粒子及其薄膜的制备与光学性能研究()
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《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2018年04期
页码:
411-418+426
栏目:
出版日期:
2018-08-20

文章信息/Info

Title:
The Synthesis and Charaterization of Two Naphthyloxy MPc/TiO2 Composite
文章编号:
1000-5862(2018)04-0411-08
作者:
赵志鹏; 曾承辉; 帅 敏; 刘 冉; 钟声亮*
江西师范大学化学化工学院,江西 南昌 330022
Author(s):
YIN Yanbing; GONG Jing; PEI Lizhou
Department of Chemistry and Chemical Engineering,Qiqihar University,Qiqihar Heilongjiang 161006,China
关键词:
配位聚合物;  稀土;  噻吩甲酰三氟丙酮;  纳米粒子;  薄膜
Keywords:
naphthyloxy metal-phthalocyanine composite;  synthesis;  characterization
分类号:
O 614.33
DOI:
10.16357/j.cnki.issn1000-5862.2018.04.16
文献标志码:
A
摘要:
采用简单的混合溶剂热、无模板剂的方法,以Eu(NO3)3·6H2O为金属离子源、噻吩甲酰三氟丙酮(HTTA)为有机配体,成功制备了噻吩甲酰三氟丙酮铕配位聚合物(Eu-CP)纳米粒子.用不同手段对合成的产物进行了表征,并对其发光性能进行了研究.通过与聚甲基丙烯酸甲酯混合,以N,N-二甲基甲酰胺为溶剂,采用旋涂法制备了系列不同原料配比的Eu-CP纳米粒子旋涂膜,并对比了它们的荧光强度.探讨了所得旋涂膜的光稳定性以及热稳定性.
Abstract:
Phthalocyanine precursor of 3-(2-naphthyloxy)phthalonitrile is synthesized and the structure is determined by 1H NMR and melting point. 3-(2-naphthyloxy)CoPc/TiO2 and 3-(2-naphthyloxy)CuPc/TiO2 are synthesized in situ.Products are characterized by IR,UV-Vis and XRD.The influence of the central metal ion and TiO2 to maximum absorption wavelength of Q-band are discussed,at the same time,TiO2 crystal form influenced by phthalocyanine is also discussed.The results show that a certain degree of red shift are found in the absorption of Q-band of composite materials,the grain size of TiO2 is decreased due to loaded phthalocyanine,but the crystal shape does not been changed.

参考文献/References:

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相似文献/References:

[1]赵永霞,聂志文,石孟孟,等.Y2 O3：Eu空心球的合成及其发光性能研究[J].江西师范大学学报(自然科学版),2015,(04):415.
　ZHAO Yongxia,NIE Zhiwen,SHI Mengmeng,et al.Y2 O3:Eu Hollow Submicrospheres:Preparation and Photoluminescence Properties[J].Journal of Jiangxi Normal University:Natural Science Edition,2015,(04):415.
[2]夏丽娟,温 慧,张 航,等.花状Fe/CeO2固溶体多级结构的合成与电化学性能研究[J].江西师范大学学报(自然科学版),2017,(06):557.
　XIA Lijuan,WEN Hui,ZHANG Hang,et al.The Synthesis and Electrochemical Performance of Flower-Like Hierarchical Fe/CeO2 Solid Solution[J].Journal of Jiangxi Normal University:Natural Science Edition,2017,(04):557.

备注/Memo

备注/Memo:
收稿日期:2018-03-16
基金项目:国家自然科学基金(91622105),江西省自然科学基金(20161BAB203083)和江西省主要学科学术和技术带头人(20172BCB22008)资助项目.
通信作者:钟声亮(1977-),男,江西赣州人,教授,主要从事稀土功能材料的研究.E-mail:slzhong@jxnu.edu.cn
更新日期/Last Update: 2018-08-20