[1]马丹阳,王 雷,李 苑,等.铕-镉异金属配位聚合物的制备及向Eu2O2S/CdS异质结转化的研究[J].江西师范大学学报(自然科学版),2016,40(04):410-414.
 MA Danyang,WANG Lei,LI Yuan,et al.The Eu-Cd Heterometallic Coordination Polymer:Preparation and Their Conversion to Eu2O2S/CdS Heterojunctions[J].,2016,40(04):410-414.
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铕-镉异金属配位聚合物的制备及向Eu2O2S/CdS异质结转化的研究()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
40
期数:
2016年04期
页码:
410-414
栏目:
出版日期:
2016-09-01

文章信息/Info

Title:
The Eu-Cd Heterometallic Coordination Polymer:Preparation and Their Conversion to Eu2O2S/CdS Heterojunctions
作者:
马丹阳王 雷李 苑钟声亮
江西师范大学化学化工学院,江西 南昌 330022
Author(s):
MA DanyangWANG LeiLI YuanZHONG Shengliang
College of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang Jiangxi 330022,China
关键词:
水热合成 配位聚合物 异质结 荧光性能
Keywords:
hydrothermal method coordination polymer heterojunction fluorescence property
分类号:
O 611.4
文献标志码:
A
摘要:
以2,3-二巯基丁二酸(DMSA)为配体,以Eu3+和Cd2+为中心金属离子,采用低温水热合成方法成功制备了粒径为20~40 nm的铕-镉异金属配位聚合物纳米粒子.在氮气氛围保护下将该配位聚合物进行热处理得到了Eu2O2S/CdS的异质结构.详细考察了煅烧温度对合成产物的影响,结果表明:温度是制备异质结材料的关键因素.对合成的产物进行了表征,并对配位聚合物的荧光性能进行了研究.
Abstract:
Eu-Cd heterometallic coordination polymer nanoparticles with diameters of 20-40 nm has been successfully synthesized by employing meso-2,3-dimercaptosuccinic acid(DMSA)as ligand and Eu3+and Cd2+as central metal ions under hydrothermal method at lower temperature.Eu2O2S/CdS heterojunctions were fabricated through a high-temperature treatment of the as-prepared coordination polymer under the N2atmosphere.The influence of calcination temperature on the synthesis of the product was investigated in detail.Results show that the temperature is the critical factor to prepare heterojunction materials.The as-prepared products were characterized using different methods.In addition,the luminescent property of the coordination polymer was also studied.

参考文献/References:

[1] Safarifard V,Morsali A.Applications of ultrasound to the synthesis of nanoscale metal-organic coordination polymers [J].Coord Chem Rev,2015,292:1-14.
[2] 乔亚莉,高楼军,陈小利,等.环状双核钴配合物的合成、晶体结构及其性质 [J].江西师范大学学报:自然科学版,2012,36(4):407-411.
[3] Zhang Xiaowei,Xing Peiqi,Geng Xiujuan,et al.Transition metal coordination polymers based on tetrabromoterephthalic and bis(imidazole)ligands:Syntheses,structures,topological analysis and photoluminescence properties [J].J Solid State Chem,2015,229:49-61.
[4] Murray L J,Dinca M,Long J R.Hydrogen storage in metal-organic frameworks [J].Chem Soc Rev,2009,38(5):1294-1314.
[5] Wang Xiaojun,Li Peizhou,Chen Yifei,et al.A rationally designed nitrogen-rich metal-organic framework and its exceptionally high CO2and H2uptake capability [J].Sci Rep,2013,3:1149.
[6] Li Jiangrong,Kuppler R J,Zhou Hongcai.Selective gas adsorption and separation in metal-organic frameworks [J].Chem Soc Rev,2009,38(5):1477-1504.
[7] Liu Jiewei,Chen Lianfen,Cui Hao,et al.Applications of metal-organic frameworks in heterogeneous supramolecular catalysis [J].Chem Soc Rev,2014,43(16):6011-6061.
[8] Corma A,Garcl’a H,Xamena F X L.Engineering metal organic frameworks for heterogeneous catalysis [J].Chem Rev,2010,110(8):4606-4655.
[9] Kreno L E,Leong K,Farha O K,et al.Metal-organic framework materials as chemical sensors [J].Chem Rev,2012,112(2):1105-1125.
[10] Zhu Xi,Zheng Hanye,Wei Xiaofeng,et al.Metal-organic framework(MOF):a novel sensing platform for biomolecules [J].Chem Commun,2013,49(13):1276-1278.
[11] Horcajada P,Gref R,Baati T,et al.Metal organicframeworks in biomedicine [J].Chem Rev,2012,112(2):1232-1268.
[12] Bencini A,Benelli C,Caneschi A,et al.Crystal and molecular structure of and magnetic coupling in two complexes containing gadolinium(III)and copper(II)ions [J].J Am Chem Soc,1985,107:8128.
[13] Shanmuga Bharathi K,Sreedaran S,Kalilur Rahiman A,et al.Synthesis and characterization of new unsymmetrical “side-off” tetra and hexa coordinate homobinuclear Cu(II)and heterobinuclear Cu(II)-Zn(II)complexes:Magnetic,electrochemical and kinetic studies [J].Spectrochim Acta A Mol Biomol Spectrosc,2012,94:334-339.
[14] Zafar H,Kareem A,Sherwani A,et al.Synthesis,characterization and biological studies of homo and hetero-binuclear 13-membered pentaaza bis(macrocyclic)complexes [J].J Mol Struct,2015,1079:337-346.
[15] Gheorghe R,Andruh M,Muller A,et al.Heterobinuclear complexes as building blocks in designing extended structures [J].Inorg Chem,2002,41(21):5314-5316.
[16] Zheng He,Cheng He,Gao Enqing,et al.Lanthanide-transition heterometallic extended structures with novel orthogonal metalloligand as building block [J].Inorg Chem,2003,42(7):2206-2208.
[17] Cai Songliang,Zheng Shengrun,Wen Zhenzhen,et al.A series of new three-dimensional d-f heterometallic coordination polymers with rare 10-connected bct net topology based on planar hexanuclear heterometallic second building units [J].Cryst Growth Des,2012,12(11):5737-5745.
[18] Zhang Yu,Huang Lian,Miao Hao,et al.Hydrothermal synthesis,structure,and optical properties of two nanosized Ln26@CO3(Ln=Dy and Tb)cluster-based lanthanide-transition-metal-organic frameworks(Ln MOFs)[J].Chem-Eur J,2015,21(8):3234-3241.
[19] Ma Cunlin,Zhang Qingfu.A supramolecular assembly of organotin complexes:syntheses,characterization and crystal structures of organotin complexes with meso-2,3-dimercaptosuccinic acid [J].Eur J Inorg Chem,2006,2006(16):3244-3254.
[20] Hu Lin,Zhang Ping,Sun Yukun,et al.ZnO/Co3O4porous nanocomposites derived from MOFs:room-temperature ferromagnetism and high catalytic oxidation of CO [J].Chem Phys Chem,2013,14(17):3953-3959.
[21] Zhong Shengliang,Jing Hongyu,Li Yuan,et al.Coordination polymer submicrospheres:fast microwave synthesis and their conversion under different atmospheres [J].Inorg Chem,2014,53(16):8278-8286.
[22] Oh M,Mirkin C A.Chemically tailorable colloidal particles from infinite coordination polymers [J].Nature,2005,438(7068):651-654.
[23] Negishi Y,Tsukuda T.One-pot preparation of subnanometer-sized gold clusters via reduction and stabilization by meso-2,3-dimercaptosuccinic acid [J].J Am Chem Soc,2003,125(14):4046-4047.
[24] Liu Xuan,Cheng Lingxiao,Lei Jianping,et al.Formation of surface traps on quantum dots by bidentate chelation and their application in low-potential electrochemiluminescent biosensing [J].Chemistry,2010,16(35):10764-10770.
[25] Ablet A,Li Shumu,Cao Wei,et al.Luminescence uuning and white-light emission of Co-doped Ln-Cd-organic frameworks [J].Chem-Asian J,2013,8(1):95-100.
[26] Liu Qi,Wan Fang,Qiu Lixia,et al.Four 2D Ln-Cd heterometal-organic coordination polymers based on tetranuclear Ln-Cd oxo-cluster with highly selective luminescent sensing of organic molecules and metal cations [J].RSC Adv,2014,4(51):27013-27021.

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备注/Memo

备注/Memo:
收稿日期:2016-04-02基金项目:国家自然科学基金(21201089,21261010,61201104),江西省教育厅科技落地计划(GJJ11382)和江西省科技厅青年科学家培养对象(20144BCB23039)资助项目.通信作者:钟声亮(1977-),男,江西赣州人,教授,博士后,主要从事稀土功能材料的研究.
更新日期/Last Update: 1900-01-01