[1]熊云奎,廖维林,涂媛鸿.石墨状聚萘的合成及其作为锂离子电池正极材料[J].江西师范大学学报(自然科学版),2015,(05):474-479.
　XIONG Yunkui,LIAO Weilin,TU Yuanhong.The Synthesis of Graphite-Like Polynaphthalene and Its Electrochemical Properties as Cathode Material for Lithium-Ion Battery[J].Journal of Jiangxi Normal University:Natural Science Edition,2015,(05):474-479.
点击复制

石墨状聚萘的合成及其作为锂离子电池正极材料()
分享到：

《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2015年05期
页码:
474-479
栏目:
出版日期:
2015-10-01

文章信息/Info

Title:
The Synthesis of Graphite-Like Polynaphthalene and Its Electrochemical Properties as Cathode Material for Lithium-Ion Battery
作者:
熊云奎；廖维林；涂媛鸿
江西师范大学化工研究中心,江西南昌,330027
Author(s):
XIONG Yunkui；LIAO Weilin；TU Yuanhong
关键词:
导电聚合物; 3; 4; 9; 10-二苯四甲酸酐; 聚萘; 锂离子电池; 正极材料
Keywords:
conductive polymer; 3; 4; 9; 10-perylenetetracarboxylic dianhydride; polynaphthalene; lithium ion battery; cathode material
分类号:
O646
文献标志码:
A
摘要:
导电聚合物材料具有原料价格低廉、比重轻、具可塑性、微结构便于控制等优点，在锂离子电池方面具有应用的潜力.聚萘是一种良好的导电高分子，它具有许多优良的光电性能.该文以3，4，9，10-二苯四甲酸酐为原料，在一定条件下，经高温煅烧合成一种石墨状聚萘，并以这种石墨状聚萘为锂离子电池正极材料，对其进行探索性研究.通过红外光谱、拉曼光谱、热失重、扫描电镜等分析手段，对合成的石墨状聚萘做了相应的结构和外貌表征；利用恒流充放电、循环伏安和交流阻抗等电化学方法来研究石墨状聚萘的电化学性能.结果表明，通过上述合成方法，成功合成了石墨状聚萘，经电化学性能测试发现石墨状聚萘有较大的放电容量、良好的循环稳定性，在电流密度为100 mAh · g-1的条件下，首次放电容量高达281.3 mAh·g-1，100次循环后，容量仍保持在188.4 mAh·g-1，容量保持率高达66.97；.因此，石墨状聚萘是一种较为理想的锂离子电池的正极材料.
Abstract:
Conductive polymer materials with the raw material price is low,the proportion of light,plasticity,the ad-vantage of easy to control microstructure,and etc,promising as electrode materials for lithium-ion secondary battery. Based on this purpose,polynaphthalene as the research object was chosened. Polynaphthalene is a kind of good con-ducting polymer,it has many excellent photoelectric properties. The synthesis of polynaphthalene is variety,while this paper chose a relatively simple synthetic method:a tubular furnace at 530℃,3 ,4 ,9 ,10-perylenetetracarboxylic dianhydride( PTCDA)long time of heating to release of CO and CO2 ,stripped of acid anhydride to generate free radicals,which undergo polymerization to produce an intermediate productⅠ,and then the intermediate productⅠat 650 ℃ further heated to lose part of hydrogen,the product Ⅱ of good electrical conductivity is generated. Com-bined with the reaction mechanism of the relevant literatures,PTCDA thermal gravimetric analysis,infrared,and IR, Raman,SEM of the product Ⅱ and graphite related test,These evidences are enough to prove that graphite-like polynaphthalene is synthesized. The graphite-like polynaphthalene electrode is the constant current charge and dis-charge test,cyclic voltammetry and Ac impedance test,through these tests,the first clear the charge and discharge platform of the polynaphthalene electrode,and find that the electrode has a larger discharge capacity and good cycle stability. The first discharge capacity is 281. 3 mAh · g-1 ,the 100th cycle,the discharge capacity remains 188. 4 mAh·g-1 ,the capacity retention rate is as high as 66. 97；. Therefore,it can be deduced the graphite-like having great potential as cathode material of lithium ion battery.

参考文献/References:

[1] 田乃林.导电高分子材料的研究与应用现状 [J].承德石油高等专科学校学报,2003,5(3):19-26.
[2] Ramasamy M S,Mahapatra S S,Cho J W.Fabrication and characterization of dry conducting polymer actuator by vapor phase polymerization of polypyrrole [J].Journal of Nanoscience and Nanotechnology,2014,14(10):7553-7557.
[3] Park K,Cho J H,Shanmuganathan K,et al.New battery strategies with a polymer/Al2O3 separator [J].Journal of Power Source,2014,263:52-58.
[4] Mallya A N,Kottokkaran R,Ramamurthy P C.Conducting polymer-carbon black nanocomposite sensor for volatile organic compounds and correlating sensor response by molecular dynamics [J].Sensors and Actuators B,2014,201:308-320.
[5] Ucan D,Kanik F E,Karatas Y,et al.Synthesis and characterization of a novel polyphosphazene and its application to biosensor in combination with a conducting polymer [J].Sensors and Actuators B,2014,201:545-554.
[6] Venugopal V,Zhang Hao,Northcutt R,et al.A thermodynamic chemomechanical constitutive model for conducting polymers [J].Sensors and Actuators B,2014,201:293-299.
[7] 穆绍林.聚苯胺电池的充放电特性 [J].科学通报,1988,33(19):1484-1486.
[8] 张爱勤,王力臻,张勇.锂离子电池正极材料聚吡咯的性能 [J].电池,2008,38(2):109-111.
[9] Ryu K S,Lee Y,Han K S,et al.The electrochemical performance of polythiophene synthesized by chemical method as the polymer battery electrode [J].Materials Chemistry and Physics,2004,84(2/3):380-384.
[10] Wang Li,Lu Xingping,Lei Shengbin,et al.Graphene-based polyaniline nanocomposites:preparation,properties and applications [J].Journal of Materials Chemistry A,2014,2(13):4491-4509.
[11] Lee W W,Lee Jongmin.Novel synthesis of high performance anode materials for lithium-ion batteries(LIBs)[J].Journal of Materials Chemistry A,2014,2:1589-1626.
[12] Guerfi A,Rottier J,Boyano I,et al.High cycling stability of zinc-anode/conducting polymer rechargeable battery with non-aqueous electrolyte [J].Journal of Power Source,2014,248:1099-1104.
[13] Killian J G,Coffey B M,Gao F.Polypyrrole composite electrodes in an all-polymer battery system [J].Journal of the Electrochemical Society,1996,143(3):936-942.
[14] Tasch S,Graupner W,Leising G,et al.Red-orange electroluminescence with new soluble and air-stable poly(naphthalene-vinylene)s [J].Advanced Materials,1995,7(11):903-906.
[15] 祖革,罗维克,吴浩青.锂在共轭双键高分子中的电化学嵌入反应:Ⅲ.锂在聚萘中的电化学嵌入反应 [J].化学学报,1999,57(5):465-471.
[16] Hara S,Toshima N.Electrochemical polymerization of naphthalene using a composite electrolyte of aluminum chloride and copper(I)chloride [J].Chemistry Letters,1990,19(2):269-272.
[17] Zhang Jiaxin,Liu Chen,Shi Gaoquan,et al.Theoretical and experimental studies on the Raman spectra of electrosynthesized polynaphthalene [J].Journal of Polymer Science,Part B:Polymer Physics,2005,43(2):241-251.
[18] Mori T,Kijima M.Synthesis and optical properties of polynaphthalene derivatives [J].Optical Materials,2007,30(4):545-552.
[19] Miao Changcheng,Zhi Jian,Sun Shiyuan,et al.Formation of conjugated polynaphthalene via Bergman cyclization [J].Journal of Polymer Science,Part A:Polymer Chemistry,2010,48(10):2187-2193.
[20] 黄美荣,高鹏,李新贵.聚萘的合成及其光电器件 [J].化学进展,2010,22(1):113-118.
[21] Kaplan M L,Schmidt P H,Chen C H,et al.Carbon films with relatively high conductivity [J].Applied Physics Letters,1980,36(10):867-869.
[22] Murakami M,Yoshimura S.Synthesis of one-dimensional graphite polymer,poly-peri-naphthalene,by vapor phase polymerization [J].Molecular Crystals and Liquid Crystals,1985,118:95-102.
[23] Murakami M,Yoshimura S.Synthesis of poly-peri-naphthalene by vapour-phase polymerization:an approach to a one-dimensional graphite [J].J Chem Soc,Chem Commun,1984,24:1649-1650.
[24] Murakami M,Iijima S,Yoshimura S.Morphology and structure of a one-dimensional graphite polymer,poly-peri-naphthalene [J].Journal of Applied Physics,1986,60:3856-3863.
[25] Murakami M,Yoshimura S,Lijima S.Structural properties of graphitized poly-peri-naphthalene whiskers [J].Applied Physics Letters,1986,48(6):390-392.
[26] Nishio S,Mase R.Preparation of amorphous organic semiconductor thin films with polyperinaphthalene structure on temperature-controlled substrates by excimer laser ablation of 3,4,9,10-perylenetetracarboxylic dianhydride [J].Applied Surface Science,1998,127:589-594.
[27] Aurbach D,Markovsky B,Shechter A,et al.A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on ethylene carbonate-dimethyl carbonate mixtures [J].Journal of Electrochemical Society,1996,143(12):3809-3820.
[28] Aurbach A,Zaban Y,Ein-Eli Y,et al.Recent studies on the correlation between surface chemistry,morphology,three-dimensional structures and performance of Li and Li-C intercalation anodes in several important electrolyte systems [J].Journal of Power Source,1997,68(1):91-96.
[29] 刘宇,王保峰,解晶莹,等.二次锂电池中SEI膜的电化学性能表征 [J].无机材料学报,2003,18(2):307-312.
[30] 郑明森,马军,董全峰,等.正极材料表面的SEI膜形成及锂离子扩散动力学 [J].电池,2007,37(3):199-200.

相似文献/References:

[1]李永双,李德江.双-三唑并[3,4-b]-[1,3,4]噻二唑类化合物的合成及抗癌活性研究[J].江西师范大学学报(自然科学版),2012,(03):297.
　LI Yong-shuang,LI De-jiang.The Synthesis and Anticancer Activities for Bis-Triazolo [3,4-b]-[1,3,4] Thiadiazole Derivatives[J].Journal of Jiangxi Normal University:Natural Science Edition,2012,(05):297.
[2]熊云奎.二氧化钛-聚萘/硫正电极的制备及其电化学性能[J].江西师范大学学报(自然科学版),2016,40(03):225.
　XIONG Yunkui.The Preparation and Electrochemical Performance of Titanium Dioxide-Polyperinaphthalene/Sulfur Cathode Material for Lithium-Sulfur Battery[J].Journal of Jiangxi Normal University:Natural Science Edition,2016,40(05):225.
[3]许文慧,杨 婷,于 颖,等.3,3'-(间苯)二醚二酐单体及其聚酰亚胺的合成与表征[J].江西师范大学学报(自然科学版),2018,(01):82.[doi:10.16357/j.cnki.issn1000-5862.2018.01.14]
　XU Wenhui,YANG Ting,YU Ying,et al.The Synthesis and Characterization of Polyimides from A Novel Synthesized 3,3'-(m-Phenylene)Dianhydride Monomer[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(05):82.[doi:10.16357/j.cnki.issn1000-5862.2018.01.14]
[4]许文慧,于 颖,杨 婷,等.新型可3D打印聚酰亚胺的制备及其性能研究[J].江西师范大学学报(自然科学版),2018,(04):405.[doi:10.16357/j.cnki.issn1000-5862.2018.04.15]
　XU Wenhui,YU Ying,YANG Ting,et al.The Synthesis and Properties of New 3D-Printable Polyimide[J].Journal of Jiangxi Normal University:Natural Science Edition,2018,(05):405.[doi:10.16357/j.cnki.issn1000-5862.2018.04.15]
[5]刘玉婷,王龙瑞,尹大伟,等.基于肉桂醛的咪唑并[2,1-b]-1,3,4-二唑Mannich碱的合成及表征[J].江西师范大学学报(自然科学版),2021,(01):75.[doi:10.16357/j.cnki.issn1000-5862.2021.01.11]
　LIU Yuting,WANG Longrui,YIN Dawei,et al.The Synthesis and Characterization of Imidazo[2,1-b]-1,3,4-Oxadiazole Mannich Bases Based on Cinnamyl Aldehyde[J].Journal of Jiangxi Normal University:Natural Science Edition,2021,(05):75.[doi:10.16357/j.cnki.issn1000-5862.2021.01.11]

备注/Memo

备注/Memo:
国家自然科学基金(2014BAE13B02，2012BAE07B00)；江西师范大学青年成长基金(
[2013]12号)
更新日期/Last Update: 1900-01-01