[1]吴 婷(989-),女,江西高安人,等.AlPO-18分子筛膜在N2/CH4体系中的分离性能研究[J].江西师范大学学报(自然科学版),2019,(06):576-581.[doi:10.16357/j.cnki.issn1000-5862.2019.06.04]
　ZHAN Tianqi,WU Ting*,SHI Yuyin,et al.The Studies on N2/CH4 Separation Performance of AlPO-18 Membranes[J].Journal of Jiangxi Normal University:Natural Science Edition,2019,(06):576-581.[doi:10.16357/j.cnki.issn1000-5862.2019.06.04]
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AlPO-18分子筛膜在N2/CH4体系中的分离性能研究()
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《江西师范大学学报》（自然科学版）[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2019年06期
页码:
576-581
栏目:
纳米材料与绿色化学
出版日期:
2019-12-10

文章信息/Info

Title:
The Studies on N2/CH4 Separation Performance of AlPO-18 Membranes
文章编号:
1000-5862(2019)06-0576-06
作者:
吴 婷(1989-); 女; 江西高安人; 助理研究员; 博士; 主要从事膜制备与膜分离应用的研究.E-mail:tingwu@jxnu.edu.cn
江西师范大学化学化工学院,先进材料研究院,分子筛膜材料国家地方联合工程实验室,江西 南昌 330022
Author(s):
ZHAN Tianqi; WU Ting*; SHI Yuyin; LI Yuqin; GUI Tian; CHEN Xiangshu*
College of Chemistry and Chemical Engineering,Institute of Advanced Materials,State-Province Joint Engineering Laboratory of Zeolite Membrane Materials,Jiangxi Normal University,Nanchang Jiangxi 330022,China
关键词:
AlPO-18分子筛膜;  DIPEA;  N2/CH4分离;  气体渗透行为
Keywords:
AlPO-18 membrane;  DIPEA;  N2/CH4 separation;  gas permeation
分类号:
TQ 028.8
DOI:
10.16357/j.cnki.issn1000-5862.2019.06.04
文献标志码:
A
摘要:
采用廉价的N,N-二异丙基乙胺(DIPEA)为结构导向剂,通过2次水热合成法,在大孔管状莫来石支撑体上成功制备出具有N2/CH4分离性能且重复性良好的AlPO-18分子筛膜.对合成的AlPO-18分子筛膜进行了不同单气体的渗透性能测试; 考察了测试压力及温度对N2、CH4在AlPO-18分子筛膜上的气体渗透行为影响.在303 K及0.1 MPa压差测试条件下,性能最佳的AlPO-18分子筛膜对N2的渗透速率及N2/CH4的理想选择性分别为0.91×10-7 mol?m-2?s-1?Pa-1和7.9.
Abstract:
High-performance and reproducible AlPO-18 membranes are successfully prepared on porous mullite support by secondary hydrothermal synthesis with a low-cost N,N-diisopropylethylamine(DIPEA)as template for N2/CH4 separation.The composed AIPO-18 membranes are measured by single-gas permeances for H2,CO2,N2,CH4,SF6.The influence of temperature and pressure drop on the permeance performance of N2/CH4 are studied.The best membrane displays a N2 single gas permeance of 0.91&215;10-7 mol?m-2?s-1?Pa-1 with the ideal selectivity of 7.9 for N2/CH4 at 303 K and a 0.1 MPa pressure drop.

参考文献/References:

[1] 赵靖舟.非常规油气有关概念、分类及资源潜力[J].天然气地球科学,2012,23(3):393-406.
[2] Baker R W.Future directions of membrane gas separation technology[J].Ind Eng Chem Res,2002,41(6):1393-1411.
[3] 徐凤银,云箭,孟复印.低碳经济促进天然气与煤层气产业快速发展[J].中国石油勘探,2011,16(2):6-11.
[4] 冯明,陈力,徐承科,等.中国煤层气资源与可持续发展战略[J].资源科学,2007,29(3):100-104.
[5] 司光耀,蔡武,张强.国内外煤层气利用现状及前景展望[J].中国煤层气,2009,6(2):44-46.
[6] 辜敏,鲜学福,张代均,等.变压吸附技术分离CH4/N2气体混合物[J].煤炭学报,2002,27(2):197-200.
[7] Zhou Li,Guo Wencai,Zhou Yaping.A feasibility study of separating CH4/N2 by adsorption[J].Chinese J Chem Eng,2002,10(5):568-561.
[8] 陈祥树,胡娜,周荣飞,等.NaA型分子筛膜的合成与渗透汽化性能研究[J].江西师范大学学报:自然科学版,2008,32(5):534-538.
[9] Giordano L,Gubis J,Kapteijn F,et al.Conceptual design of membrane-based pre-combustion CO2 capture process:role of permeance and selectivity on performance and costs[J].J Membr Sci,2019,575:229-241.
[10] Pham T D,Liu Qingling,Lobo R F.Carbon dioxide and nitrogen adsorption on cation-exchanged SSZ-13 zeolites[J].Langmuir,2012,29(2):832-839.
[11] 周荣飞,胡娜,袁慧,等.T型分子筛膜的合成、表征和渗透汽化性能研究[J].无机化学学报,2009,25(8):1439-1446.
[12] Wilson S T,Lok B M,Messina C A,et al.Aluminophosphate molecular sieves:a new class of microporous crystalline inorganic solids[J].J Am Chem Soc,1982,104(4):1146-1147.
[13] Yu Jihong,Xu Ruren.Insight into the construction of open-framework aluminophosphates[J].Chem Soc Rev,2006,35(7):593-604.
[14] van Heyden H,Mintova S,Bein T.AIPO-18 nanocrystals synthesized under microwave irradiation[J].J Mater Chem,2006,16(5):514-518.
[15] Carreon M L,Li Shiguang,Carreon M A.AlPO-18 membranes for CO2/CH4 separation[J].Chem Commun,2012,48(17):2310-2312.
[16] Zong Zhaowang,Elsaidi S K,Thallapally P K,et al.Highly permeable AlPO-18 membranes for N2/CH4 separation[J].Ind Eng Chem Res,2017,56(14):4113-4118.
[17] Hasegawa Y,Abe C,Ikeda T,et al.Influence of change in the unit cell parameters on permeation properties of AEI-type zeolite membrane[J].J Membr Sci,2016,499:538-543.
[18] 张飞,桂田,柳波,等.高通量T型分子筛膜的制备[J].江西师范大学学报:自然科学版,2013,37(6):589-593.
[19] 郑艺鸿,布娜,袁晓蕾,等.SSZ-13分子筛膜在CO2/N2体系中的分离性能研究[J].江西师范大学学报:自然科学版,2015,39(4):411-414.
[20] Kalipcilar H,Bowen T C,Noble R D,et al.Synthesis and separation performance of SSZ-13 zeolite membranes on tubular supports[J].Chem Mater,2002,14(8):3458-3464.
[21] Bakker W J W,van Den Broeke L J P,Kapteijn F,et al.Temperature dependence of one-component permeation through a silicalite-1 membrane[J].AIChE J,1997,43(9):2203-2214.
[22] Poshusta J C,Tuan V A,Pape E A,et al.Separation of light gas mixtures using SAPO-34[J].AIChE J,2000,46(4):779-789.

备注/Memo

备注/Memo:
收稿日期:2019-07-20
基金项目:国家国际合作重大专项(2015DFA50190),国家自然科学基金(21968009)和江西省科技厅科技课题(20192ACB80003,20192BBH80024)资助项目.
通信作者:陈祥树(1966-),男,江西玉山人,教授,博士,博士生导师,主要从事膜分离与非均相催化的研究.E-mail:cxs66@jxnu.edu.cn
更新日期/Last Update: 2019-12-10