[1]时文中,徐启杰,刘雷英,等.曲克芦丁-Pd/Ce双金属催化剂对Heck反应催化性能研究[J].江西师范大学学报(自然科学版),2012,(02):189-192.
 SHI Wen-zhong,XU Qi-jie,LIU Lei-ying,et al.Catalytic Properties of Troxerutin-Pd/Ce Bimetallic Catalyst for Heck Reaction[J].,2012,(02):189-192.
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曲克芦丁-Pd/Ce双金属催化剂对Heck反应催化性能研究()
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《江西师范大学学报》(自然科学版)[ISSN:1006-6977/CN:61-1281/TN]

卷:
期数:
2012年02期
页码:
189-192
栏目:
出版日期:
2012-03-01

文章信息/Info

Title:
Catalytic Properties of Troxerutin-Pd/Ce Bimetallic Catalyst for Heck Reaction
作者:
时文中;徐启杰;刘雷英;刘大勇;崔元臣
黄淮学院化学化工系,河南驻马店,463000;黄淮学院化学化工系,河南驻马店463000;河南大学特种功能材料重点实验室,河南开封475000;河南大学特种功能材料重点实验室,河南开封,475000
Author(s):
SHI Wen-zhong;XU Qi-jie;LIU Lei-ying;LIU Da-yong;CUI Yuan-chen
关键词:
曲克芦丁氯化钯氧化铈催化Heck反应
Keywords:
troxerutin palladium chloride ceric oxid catalysis Heck reaction
分类号:
O657.3
文献标志码:
A
摘要:
制备了曲克芦丁-Pd/Ce双金属配合物催化剂,考察了催化剂对芳基卤和取代基芳基卤与丙烯酸的 Heck芳基化反应的催化性能.结果表明:在反应温度为80℃、反应时间为8h、TBABr作为溶剂和三丁胺作为碱的条件下,曲克芦丁-Pd/Ce双金属配合物能够有效地催化Heck芳基化反应,产率达85;以上.该催化剂对不同取代基芳基卤与丙烯酸的Heck反应也有很好的催化性能.
Abstract:
The bimetallic complex of troxerutin-Pd/Ce was synthesized. The catalytic properties of complex were researched for Heck reaction of phenyl halide and substituted phenyl halide with acrylic acid.The results showed that the complex can catalyzed Heck reaction in the conditions of temperature 80 ℃, time 8 h, solvent TBABr, alkali Bu3N, and the yield can reach 85% above. It can also catalyzed the Heck reaction of substituted phenyl halide with acrylic acid well.

参考文献/References:

[1] Hardy J J, Hubeas M D. Chitosan based heterogeneous catalysts for Suzuki and Heck reaction [J]. Green Chemistry, 2004, 6(1): 53-56.
[2] Heck R F, Nolly J P. Palladium catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides [J].J Org Chern, 1972, 37(14): 2320-2322.
[3] Chandrasekhar V, Athimoolam A. New hybrid inorganic-organic polymers as supports for heterogeneous catalysis: A novel Pd(0) metalated cyclophosphazene-containing polymer as an efficient heterogeneous catalyst for the Heck reaction [J]. Org Lett, 2002, 4(12): 2113-2116.
[4] Dahan A, Portnoy M. Remarkable dendritic effect in the polymer supported catalysis of the Heck arylation of olefins [J]. Org Lett, 2003, 5(8): 1197-1200.
[5] 赵文善, 崔元臣, 刘忠奎, 等. 荧光增白剂4, 4′-二-(4-磺酸钠苯乙烯基)二苯甲酮的合成 [J]. 化学研究, 2010, 21(5): 33-35.
[6] Lin Kunhua, Song Maoping, Cai Dongmei, et a1. Polymer(Fiber)-supported palladium catalyst containing imidazolinyl rings and its application to the Heck reaction [J]. Tetrahedron Lett, 2003, 44(20): 3955-3957.
[7] 徐启杰, 崔元臣, 马志华. 腐植酸负载金属配合物对Heck反应的催化性能 [J]. 化学研究, 2007, 18(4): 37-40.
[8] 孙强, 张振权, 苏永成, 等. 用正交试验选择多核钯镍(1︰1) 酞菁对Heck反应的最佳催化条件 [J]. 东北师范大学学报: 自然科学版, 1994(2): 53-56.
[9] 刘蒲, 王岚, 刘一真. 壳聚糖钯催化Heck反应合成肉桂酸丁酯的研究 [J]. 分子催化, 2004, 8(4): 275-280.
[10] 崔元臣, 张磊. 田菁胶负载钯催化Heck反应的研究 [J]. 高分子学报, 2005(3): 423-426.
[11] Artok L, Bulut H. Heterogeneous Suzuki reactions catalyzed by Pd(0)-Y zeolite [J]. Tetrahedron Lett, 2004, 45(20): 3881-3884.
[12] Pawelec B, M ariscal R, Navarro R M, et al. Performance of Si-modified Pd catalyst in acetylene hydrogenation: the origin of the ethylene selectivity improvement [J]. Appl Catal, 2002, 223(2): 161-172.
[13] Corma A, Garcia H, Leyva A, et al. Basic zeolites containing palladium as bifunctional heterogeneous catalysts for the Heck reaction [J]. Appl Catal A, 2003, 247(1): 41-49.
[14] Choi S H, Lee J S. XAFS study of tin modification of supposed palladium catalyst for 1,3-butadiene hydrogenation in the presence of 1-butene [J]. Catalysis, 2000, 193(2): 176-185.
[15] Heidenreich R G, Krauter J, Pietsch J, et al. Control of Pd leaching in Heck reactions of bromoarenes catalyzed by Pd supported on activated carbon [J]. Mol Catal, 2002, 182(2): 499-509.
[16] Sedat Y, Ismail Z, Bekir Y. 1, 3-二烷基咪唑/Pd催化卤代芳烃的Heck和Suzuki反应 [J]. 催化学报, 2008, 29(2): 185-189.
[17] 周健民, 周仁贤, 郑小明. 介孔MCM-41分子筛载钯配合物催化Heck反应的性能 [J]. 化学通报, 2002, (7): 472-475.
[18] 孙强, 姚小华, 苏永成, 等. 多核钯(Ⅱ)-镍(Ⅱ)(1: 1)酞菁对Heck反应的催化研究 [J]. 合成化学, 1994(2): 282-288.
[19] Reetz M T, Breinbauer R,Wanninger K.Suzuki and Heck reactions catalyzed by preformed palladium clusters and palladiu?mnickel bimetallic clusters [J]. Tetrahedron Lett, 1996, 37(26): 4499-4502.
[20] 徐启杰, 周大鹏, 崔元臣. 腐植酸负载Pd/Ni双金属催化剂对Heck反应催化性能的研究 [J]. 有机化学, 2007, 27(12): 1520- 1524.
[21] 杨元法, 曾朝霞, 罗孟飞, 等, 胺基化树脂负载Pd(0)对Heck反应催化性能的研究 [J]. 化学学报, 2005, 63(16): 1469- 1473.
[22] Iweta P R, Anna M T, Jozef J Z. Base-free efficient palladium catalyst of Heck reaction in molten tetrabutylammonium bromide [J]. J Mol Catal A Chem, 2006, 257(1/2): 3-8.

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更新日期/Last Update: 1900-01-01